Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation

A major problem that limits the use of biodiesel is maintaining the fuel at the specified standards for a longer period. Biodiesel oxidizes much more easily than diesel, and the final oxidation products change its physical and chemical properties and cause the formation of insoluble gums that can bl...

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Main Authors: Elena David, Janez Kopac
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/23/7765
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author Elena David
Janez Kopac
author_facet Elena David
Janez Kopac
author_sort Elena David
collection DOAJ
description A major problem that limits the use of biodiesel is maintaining the fuel at the specified standards for a longer period. Biodiesel oxidizes much more easily than diesel, and the final oxidation products change its physical and chemical properties and cause the formation of insoluble gums that can block fuel filters and the supply pipes. This instability of biodiesel is a major problem and has not yet been satisfactorily resolved. Recently, the use of biodiesel has increased quite a lot, but the problem related to oxidation could become a significant impediment. A promising and cost-effective approach to improving biodiesel’s stability is to add appropriate antioxidants. Antioxidants work better or less effectively in different biodiesel fuels, and there is no one-size-fits-all inhibitor for every type of biodiesel fuel. To establish a suitable antioxidant for a certain type of biodiesel, it is necessary to know the chemistry of the antioxidants and factors that influence their effectiveness against biodiesel oxidation. Most studies on the use of antioxidants to improve the oxidative stability of biodiesel have been conducted independently. This study presents an analysis of these studies and mentions factors that must be taken into account for the choice of antioxidants so that the storage stability of biodiesel fuels can be improved.
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spelling doaj.art-2fd818737d644395868aa9d359afc34c2023-12-08T15:22:16ZengMDPI AGMolecules1420-30492023-11-012823776510.3390/molecules28237765Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through OxidationElena David0Janez Kopac1National Institute for Research and Development for Cryogenic and Isotopic Technologies, Street Uzinei No. 4, P.O. Râureni, P.O. Box 7, 240050 Ramnicu Valcea, RomaniaFaculty of Mechanical Engineering, University of Ljubljana, Askerceva 6, SI-1000 Ljubljana, SloveniaA major problem that limits the use of biodiesel is maintaining the fuel at the specified standards for a longer period. Biodiesel oxidizes much more easily than diesel, and the final oxidation products change its physical and chemical properties and cause the formation of insoluble gums that can block fuel filters and the supply pipes. This instability of biodiesel is a major problem and has not yet been satisfactorily resolved. Recently, the use of biodiesel has increased quite a lot, but the problem related to oxidation could become a significant impediment. A promising and cost-effective approach to improving biodiesel’s stability is to add appropriate antioxidants. Antioxidants work better or less effectively in different biodiesel fuels, and there is no one-size-fits-all inhibitor for every type of biodiesel fuel. To establish a suitable antioxidant for a certain type of biodiesel, it is necessary to know the chemistry of the antioxidants and factors that influence their effectiveness against biodiesel oxidation. Most studies on the use of antioxidants to improve the oxidative stability of biodiesel have been conducted independently. This study presents an analysis of these studies and mentions factors that must be taken into account for the choice of antioxidants so that the storage stability of biodiesel fuels can be improved.https://www.mdpi.com/1420-3049/28/23/7765biodiesel stabilityoxidationantioxidantsantioxidant mechanismcold flow
spellingShingle Elena David
Janez Kopac
Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
Molecules
biodiesel stability
oxidation
antioxidants
antioxidant mechanism
cold flow
title Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
title_full Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
title_fullStr Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
title_full_unstemmed Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
title_short Survey on Antioxidants Used as Additives to Improve Biodiesel’s Stability to Degradation through Oxidation
title_sort survey on antioxidants used as additives to improve biodiesel s stability to degradation through oxidation
topic biodiesel stability
oxidation
antioxidants
antioxidant mechanism
cold flow
url https://www.mdpi.com/1420-3049/28/23/7765
work_keys_str_mv AT elenadavid surveyonantioxidantsusedasadditivestoimprovebiodieselsstabilitytodegradationthroughoxidation
AT janezkopac surveyonantioxidantsusedasadditivestoimprovebiodieselsstabilitytodegradationthroughoxidation