Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)

Evaporation process affecting brines in salar of Huasco (Chile) has been reproduced at laboratory scale with the main objective of studying its geochemical evolving path. Natural brines have been evaporated under isothermal conditions, precipitating progressively calcite, gypsum, thenardite, and ha...

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Main Authors: Ingrid Garcés Millas, Pedro López Julián
Format: Article
Language:English
Published: Universidad de Antioquia 2013-03-01
Series:Revista Facultad de Ingeniería Universidad de Antioquia
Subjects:
Online Access:https://revistas.udea.edu.co/index.php/ingenieria/article/view/14809
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author Ingrid Garcés Millas
Pedro López Julián
author_facet Ingrid Garcés Millas
Pedro López Julián
author_sort Ingrid Garcés Millas
collection DOAJ
description Evaporation process affecting brines in salar of Huasco (Chile) has been reproduced at laboratory scale with the main objective of studying its geochemical evolving path. Natural brines have been evaporated under isothermal conditions, precipitating progressively calcite, gypsum, thenardite, and halite. This mineral sequence confirms the evolution of equilibrium conditions calculated by means of PHRQPITZ geochemical code. Geochemical modeling has allowed to determine that saline minerals reach saturation along the experiment performed at different evolutive moments that they do in natural conditions. This fact is due to two main causes, first to the interaction between dilute solutions entering salar with the external saline rim mainly composed of gypsum, whose solubilization causes that brines reach faster saturation respect to gypsum in the natural system compared to experiments in laboratory; and second, to precipitation of mirabilite as consequence of thermal oscillations to daily scale causing that halite equilibrium is reached for higher brine concentrations in salar that in laboratory, since mirabilite precipitation produces a significant depletion of sodium concentration in brines.
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spelling doaj.art-2fefc9b5f1cd4fae8fa0e36f7fde678c2023-03-23T12:35:22ZengUniversidad de AntioquiaRevista Facultad de Ingeniería Universidad de Antioquia0120-62302422-28442013-03-0152Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)Ingrid Garcés Millas0Pedro López Julián1University of AntofagastaUniversity of Zaragoza Evaporation process affecting brines in salar of Huasco (Chile) has been reproduced at laboratory scale with the main objective of studying its geochemical evolving path. Natural brines have been evaporated under isothermal conditions, precipitating progressively calcite, gypsum, thenardite, and halite. This mineral sequence confirms the evolution of equilibrium conditions calculated by means of PHRQPITZ geochemical code. Geochemical modeling has allowed to determine that saline minerals reach saturation along the experiment performed at different evolutive moments that they do in natural conditions. This fact is due to two main causes, first to the interaction between dilute solutions entering salar with the external saline rim mainly composed of gypsum, whose solubilization causes that brines reach faster saturation respect to gypsum in the natural system compared to experiments in laboratory; and second, to precipitation of mirabilite as consequence of thermal oscillations to daily scale causing that halite equilibrium is reached for higher brine concentrations in salar that in laboratory, since mirabilite precipitation produces a significant depletion of sodium concentration in brines. https://revistas.udea.edu.co/index.php/ingenieria/article/view/14809Huasco salar's evaporationgeochemistrynatural brinesPHRQPITZsaturation
spellingShingle Ingrid Garcés Millas
Pedro López Julián
Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
Revista Facultad de Ingeniería Universidad de Antioquia
Huasco salar's
evaporation
geochemistry
natural brines
PHRQPITZ
saturation
title Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
title_full Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
title_fullStr Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
title_full_unstemmed Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
title_short Monitoring geochemistry of the evolution of natural system: salar de Huasco (Chile)
title_sort monitoring geochemistry of the evolution of natural system salar de huasco chile
topic Huasco salar's
evaporation
geochemistry
natural brines
PHRQPITZ
saturation
url https://revistas.udea.edu.co/index.php/ingenieria/article/view/14809
work_keys_str_mv AT ingridgarcesmillas monitoringgeochemistryoftheevolutionofnaturalsystemsalardehuascochile
AT pedrolopezjulian monitoringgeochemistryoftheevolutionofnaturalsystemsalardehuascochile