Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
Mixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation metho...
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Format: | Article |
Language: | English |
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Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2002-09-01
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Series: | Materials Research |
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Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=en |
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author | Sania Maria de Lima José Mansur Assaf |
author_facet | Sania Maria de Lima José Mansur Assaf |
author_sort | Sania Maria de Lima |
collection | DOAJ |
description | Mixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation method to be used in the methane reforming to produce hydrogen and synthesis gas. The compounds were characterized by X-ray diffraction, thermogravimetric and differential thermal analysis, inductively coupled plasma atomic emission spectroscopy, surface area measurements, energy dispersive X-ray spectrometry coupled to scanning electron microscopy and temperature programmed reduction. The results showed that a suitable combination of the preparation method with calcination variables (time and temperature) could result in oxides with the desired structure and with important properties at the application point of view in heterogeneous catalysis. |
first_indexed | 2024-12-24T01:40:08Z |
format | Article |
id | doaj.art-2ff16277826343d5b4671cb106e6a5ad |
institution | Directory Open Access Journal |
issn | 1516-1439 |
language | English |
last_indexed | 2024-12-24T01:40:08Z |
publishDate | 2002-09-01 |
publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
record_format | Article |
series | Materials Research |
spelling | doaj.art-2ff16277826343d5b4671cb106e6a5ad2022-12-21T17:22:04ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392002-09-015332933510.1590/S1516-14392002000300018Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis ApplicationSania Maria de Lima0José Mansur Assaf1Universidade Federal de São CarlosUniversidade Federal de São CarlosMixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation method to be used in the methane reforming to produce hydrogen and synthesis gas. The compounds were characterized by X-ray diffraction, thermogravimetric and differential thermal analysis, inductively coupled plasma atomic emission spectroscopy, surface area measurements, energy dispersive X-ray spectrometry coupled to scanning electron microscopy and temperature programmed reduction. The results showed that a suitable combination of the preparation method with calcination variables (time and temperature) could result in oxides with the desired structure and with important properties at the application point of view in heterogeneous catalysis.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=enLaNiO3Perovskiteprecipitationcatalysis |
spellingShingle | Sania Maria de Lima José Mansur Assaf Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application Materials Research LaNiO3 Perovskite precipitation catalysis |
title | Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application |
title_full | Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application |
title_fullStr | Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application |
title_full_unstemmed | Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application |
title_short | Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application |
title_sort | synthesis and characterization of lanio3 lani 1 x fe xo3 andlani 1 x co xo3 perovskite oxides for catalysis application |
topic | LaNiO3 Perovskite precipitation catalysis |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=en |
work_keys_str_mv | AT saniamariadelima synthesisandcharacterizationoflanio3lani1xfexo3andlani1xcoxo3perovskiteoxidesforcatalysisapplication AT josemansurassaf synthesisandcharacterizationoflanio3lani1xfexo3andlani1xcoxo3perovskiteoxidesforcatalysisapplication |