Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application

Mixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation metho...

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Main Authors: Sania Maria de Lima, José Mansur Assaf
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2002-09-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=en
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author Sania Maria de Lima
José Mansur Assaf
author_facet Sania Maria de Lima
José Mansur Assaf
author_sort Sania Maria de Lima
collection DOAJ
description Mixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation method to be used in the methane reforming to produce hydrogen and synthesis gas. The compounds were characterized by X-ray diffraction, thermogravimetric and differential thermal analysis, inductively coupled plasma atomic emission spectroscopy, surface area measurements, energy dispersive X-ray spectrometry coupled to scanning electron microscopy and temperature programmed reduction. The results showed that a suitable combination of the preparation method with calcination variables (time and temperature) could result in oxides with the desired structure and with important properties at the application point of view in heterogeneous catalysis.
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publishDate 2002-09-01
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spelling doaj.art-2ff16277826343d5b4671cb106e6a5ad2022-12-21T17:22:04ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392002-09-015332933510.1590/S1516-14392002000300018Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis ApplicationSania Maria de Lima0José Mansur Assaf1Universidade Federal de São CarlosUniversidade Federal de São CarlosMixed metal oxides with perovskite-type structure show a great potential to be used in catalysis, electrocatalysis and electronic ceramics. Perovskites oxides catalysts with the composition LaNiO3, LaNi(1-x)Fe xO3 and LaNi(1-x)Co xO3 (x = 0.4 and 0.7) have been synthesized by the precipitation method to be used in the methane reforming to produce hydrogen and synthesis gas. The compounds were characterized by X-ray diffraction, thermogravimetric and differential thermal analysis, inductively coupled plasma atomic emission spectroscopy, surface area measurements, energy dispersive X-ray spectrometry coupled to scanning electron microscopy and temperature programmed reduction. The results showed that a suitable combination of the preparation method with calcination variables (time and temperature) could result in oxides with the desired structure and with important properties at the application point of view in heterogeneous catalysis.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=enLaNiO3Perovskiteprecipitationcatalysis
spellingShingle Sania Maria de Lima
José Mansur Assaf
Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
Materials Research
LaNiO3
Perovskite
precipitation
catalysis
title Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
title_full Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
title_fullStr Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
title_full_unstemmed Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
title_short Synthesis and Characterization of LaNiO3, LaNi(1-x)Fe xO3 andLaNi(1-x)Co xO3 Perovskite Oxides for Catalysis Application
title_sort synthesis and characterization of lanio3 lani 1 x fe xo3 andlani 1 x co xo3 perovskite oxides for catalysis application
topic LaNiO3
Perovskite
precipitation
catalysis
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392002000300018&tlng=en
work_keys_str_mv AT saniamariadelima synthesisandcharacterizationoflanio3lani1xfexo3andlani1xcoxo3perovskiteoxidesforcatalysisapplication
AT josemansurassaf synthesisandcharacterizationoflanio3lani1xfexo3andlani1xcoxo3perovskiteoxidesforcatalysisapplication