| Summary: | In the title molecular salt, C6H10N22+·2ClO4−, the Cl—O bond lengths [anion 1: 1.369 (3)–1.415 (3); anion 2: 1.420 (2)–1.441 (2) Å] and the O—Cl—O angles [anion 1: 105.4 (2)–111.8 (4); anion 2: 107.8 (1)–110.3 (1)°] indicate a slight distortion of the perchlorate anions from regular tetrahedral symmetry. In the crystal, the components are linked into columns along the a-axis direction via N—H...O and C—H...O hydrogen bonds, with stacks of the organic molecules being surrounded by stacks of perchlorate anions.
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