Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion
Olefin migratory insertion into a metal–hydrogen or a metal–carbon bond is an ubiquitous step in olefin coordination catalysis by transition metal complexes. When the catalytic system has element(s) of chirality, and when the two carbon atoms of the substrate are not symmetry-related, the...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
2001-10-01
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| Series: | CHIMIA |
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| Online Access: | https://www.chimia.ch/chimia/article/view/3490 |
| _version_ | 1818294308326866944 |
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| author | Giambattista Consiglio |
| author_facet | Giambattista Consiglio |
| author_sort | Giambattista Consiglio |
| collection | DOAJ |
| description |
Olefin migratory insertion into a metal–hydrogen or a metal–carbon bond is an ubiquitous step in olefin coordination catalysis by transition metal complexes. When the catalytic system has element(s) of chirality, and when the two carbon atoms of the substrate are not symmetry-related,
the nature of the reaction products will be determined by the capacity of the catalytic system for enantioface selection and by the direction of the insertion. Despite some progress having been made, good control of this important catalytic step is far from being realized. Considerations concerning
this step are presented with particular reference to the work of the author in the field of hydrocarbonylation and olefin (co)polymerization reactions.
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| first_indexed | 2024-12-13T03:29:41Z |
| format | Article |
| id | doaj.art-3016ae66371c47c5ad38b7215cc09e75 |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-12-13T03:29:41Z |
| publishDate | 2001-10-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-3016ae66371c47c5ad38b7215cc09e752022-12-22T00:01:11ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242001-10-015510Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory InsertionGiambattista Consiglio Olefin migratory insertion into a metal–hydrogen or a metal–carbon bond is an ubiquitous step in olefin coordination catalysis by transition metal complexes. When the catalytic system has element(s) of chirality, and when the two carbon atoms of the substrate are not symmetry-related, the nature of the reaction products will be determined by the capacity of the catalytic system for enantioface selection and by the direction of the insertion. Despite some progress having been made, good control of this important catalytic step is far from being realized. Considerations concerning this step are presented with particular reference to the work of the author in the field of hydrocarbonylation and olefin (co)polymerization reactions. https://www.chimia.ch/chimia/article/view/3490CarbonylationMigratory insertionOlefinsPolymerizationTransition metal catalysis |
| spellingShingle | Giambattista Consiglio Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion CHIMIA Carbonylation Migratory insertion Olefins Polymerization Transition metal catalysis |
| title | Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion |
| title_full | Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion |
| title_fullStr | Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion |
| title_full_unstemmed | Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion |
| title_short | Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion |
| title_sort | transition metal catalysis on olefins some considerations relative to migratory insertion |
| topic | Carbonylation Migratory insertion Olefins Polymerization Transition metal catalysis |
| url | https://www.chimia.ch/chimia/article/view/3490 |
| work_keys_str_mv | AT giambattistaconsiglio transitionmetalcatalysisonolefinssomeconsiderationsrelativetomigratoryinsertion |