Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
In this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD...
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Elsevier
2016-09-01
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Series: | Boletín de la Sociedad Española de Cerámica y Vidrio |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S036631751630070X |
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author | Yazid Boudjadja Abderrezak Amira Abdelmalek Saoudel Nabil Mahamdioua Ahmet Varilci Cabir Terzioglu Sevgi Polat Altintas |
author_facet | Yazid Boudjadja Abderrezak Amira Abdelmalek Saoudel Nabil Mahamdioua Ahmet Varilci Cabir Terzioglu Sevgi Polat Altintas |
author_sort | Yazid Boudjadja |
collection | DOAJ |
description | In this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) combined with EDS spectroscopy, density, Vickers microhardness and resistivity measurements. A good correlation between the variations of the bulk density and the Vickers microhardness with doping is obtained. The SEM photograph shows that the samples are composed of grains with a flat shape that characterizes the Bi-based cuprates. Quantitative EDS analysis confirms the reduction of Ca content and the increase of Y content when x is increased. The variation of resistivity with temperature shows that only samples with x = 0, 0.025 and 0.05 present an onset transition to the superconducting state. The higher onset transition temperature is obtained for x = 0.025 and is about 93.62 K. The transition is wide and is realized in two steps confirming then the presence of the low Tc Bi-2201 phase in the samples. For x = 0.075 and 0.10, a transition to a semiconducting state is seen at low temperatures. Some physical parameters are extracted from these curves and discussed. |
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issn | 0366-3175 |
language | English |
last_indexed | 2024-12-12T08:19:49Z |
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series | Boletín de la Sociedad Española de Cerámica y Vidrio |
spelling | doaj.art-302871c89ad34438a5fe789b2eba59ef2022-12-22T00:31:26ZengElsevierBoletín de la Sociedad Española de Cerámica y Vidrio0366-31752016-09-0155520220810.1016/j.bsecv.2016.07.003Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramicsYazid Boudjadja0Abderrezak Amira1Abdelmalek Saoudel2Nabil Mahamdioua3Ahmet Varilci4Cabir Terzioglu5Sevgi Polat Altintas6NDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyIn this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) combined with EDS spectroscopy, density, Vickers microhardness and resistivity measurements. A good correlation between the variations of the bulk density and the Vickers microhardness with doping is obtained. The SEM photograph shows that the samples are composed of grains with a flat shape that characterizes the Bi-based cuprates. Quantitative EDS analysis confirms the reduction of Ca content and the increase of Y content when x is increased. The variation of resistivity with temperature shows that only samples with x = 0, 0.025 and 0.05 present an onset transition to the superconducting state. The higher onset transition temperature is obtained for x = 0.025 and is about 93.62 K. The transition is wide and is realized in two steps confirming then the presence of the low Tc Bi-2201 phase in the samples. For x = 0.075 and 0.10, a transition to a semiconducting state is seen at low temperatures. Some physical parameters are extracted from these curves and discussed.http://www.sciencedirect.com/science/article/pii/S036631751630070XBi-2202 phaseCuprate ceramicsDopingStructureSuperconductors |
spellingShingle | Yazid Boudjadja Abderrezak Amira Abdelmalek Saoudel Nabil Mahamdioua Ahmet Varilci Cabir Terzioglu Sevgi Polat Altintas Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics Boletín de la Sociedad Española de Cerámica y Vidrio Bi-2202 phase Cuprate ceramics Doping Structure Superconductors |
title | Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics |
title_full | Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics |
title_fullStr | Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics |
title_full_unstemmed | Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics |
title_short | Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics |
title_sort | effect of yttrium doping on structural and electrical properties of bi2sr1 9ca0 1 xyxcu2o7 δ bi 2202 cuprate ceramics |
topic | Bi-2202 phase Cuprate ceramics Doping Structure Superconductors |
url | http://www.sciencedirect.com/science/article/pii/S036631751630070X |
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