Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics

In this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD...

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Main Authors: Yazid Boudjadja, Abderrezak Amira, Abdelmalek Saoudel, Nabil Mahamdioua, Ahmet Varilci, Cabir Terzioglu, Sevgi Polat Altintas
Format: Article
Language:English
Published: Elsevier 2016-09-01
Series:Boletín de la Sociedad Española de Cerámica y Vidrio
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S036631751630070X
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author Yazid Boudjadja
Abderrezak Amira
Abdelmalek Saoudel
Nabil Mahamdioua
Ahmet Varilci
Cabir Terzioglu
Sevgi Polat Altintas
author_facet Yazid Boudjadja
Abderrezak Amira
Abdelmalek Saoudel
Nabil Mahamdioua
Ahmet Varilci
Cabir Terzioglu
Sevgi Polat Altintas
author_sort Yazid Boudjadja
collection DOAJ
description In this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) combined with EDS spectroscopy, density, Vickers microhardness and resistivity measurements. A good correlation between the variations of the bulk density and the Vickers microhardness with doping is obtained. The SEM photograph shows that the samples are composed of grains with a flat shape that characterizes the Bi-based cuprates. Quantitative EDS analysis confirms the reduction of Ca content and the increase of Y content when x is increased. The variation of resistivity with temperature shows that only samples with x = 0, 0.025 and 0.05 present an onset transition to the superconducting state. The higher onset transition temperature is obtained for x = 0.025 and is about 93.62 K. The transition is wide and is realized in two steps confirming then the presence of the low Tc Bi-2201 phase in the samples. For x = 0.075 and 0.10, a transition to a semiconducting state is seen at low temperatures. Some physical parameters are extracted from these curves and discussed.
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spelling doaj.art-302871c89ad34438a5fe789b2eba59ef2022-12-22T00:31:26ZengElsevierBoletín de la Sociedad Española de Cerámica y Vidrio0366-31752016-09-0155520220810.1016/j.bsecv.2016.07.003Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramicsYazid Boudjadja0Abderrezak Amira1Abdelmalek Saoudel2Nabil Mahamdioua3Ahmet Varilci4Cabir Terzioglu5Sevgi Polat Altintas6NDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaNDT Lab, Faculty of Science and Technology, Jijel University, Jijel 18000, AlgeriaDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyDepartment of Physics, Faculty of Arts and Sciences, AIB University, Bolu 14280, TurkeyIn this work, we report on the effect of Y3+ doping on structural, mechanical and electrical properties of Bi-2202 phase. Samples of Bi2Sr1.9Ca0.1−xYxCu2O7+δ with x = 0, 0.025, 0.05, 0.075 and 0.10 are elaborated in air by conventional solid state reaction and characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) combined with EDS spectroscopy, density, Vickers microhardness and resistivity measurements. A good correlation between the variations of the bulk density and the Vickers microhardness with doping is obtained. The SEM photograph shows that the samples are composed of grains with a flat shape that characterizes the Bi-based cuprates. Quantitative EDS analysis confirms the reduction of Ca content and the increase of Y content when x is increased. The variation of resistivity with temperature shows that only samples with x = 0, 0.025 and 0.05 present an onset transition to the superconducting state. The higher onset transition temperature is obtained for x = 0.025 and is about 93.62 K. The transition is wide and is realized in two steps confirming then the presence of the low Tc Bi-2201 phase in the samples. For x = 0.075 and 0.10, a transition to a semiconducting state is seen at low temperatures. Some physical parameters are extracted from these curves and discussed.http://www.sciencedirect.com/science/article/pii/S036631751630070XBi-2202 phaseCuprate ceramicsDopingStructureSuperconductors
spellingShingle Yazid Boudjadja
Abderrezak Amira
Abdelmalek Saoudel
Nabil Mahamdioua
Ahmet Varilci
Cabir Terzioglu
Sevgi Polat Altintas
Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
Boletín de la Sociedad Española de Cerámica y Vidrio
Bi-2202 phase
Cuprate ceramics
Doping
Structure
Superconductors
title Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
title_full Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
title_fullStr Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
title_full_unstemmed Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
title_short Effect of yttrium doping on structural and electrical properties of Bi2Sr1.9Ca0.1−xYxCu2O7+δ (Bi-2202) cuprate ceramics
title_sort effect of yttrium doping on structural and electrical properties of bi2sr1 9ca0 1 xyxcu2o7 δ bi 2202 cuprate ceramics
topic Bi-2202 phase
Cuprate ceramics
Doping
Structure
Superconductors
url http://www.sciencedirect.com/science/article/pii/S036631751630070X
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