Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells

A novel family of iodide salts and ionic liquids based on different carbohydrate core units is herein described for application in dye-sensitized solar cell (DSC). The influence of the molecular skeleton and the cationic structure on the electrolyte properties, device performance and on interfacial...

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Main Authors: Iryna Sagaidak, Guillaume Huertas, Albert Nguyen Van Nhien, Frédéric Sauvage
Format: Article
Language:English
Published: MDPI AG 2016-03-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/9/4/241
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author Iryna Sagaidak
Guillaume Huertas
Albert Nguyen Van Nhien
Frédéric Sauvage
author_facet Iryna Sagaidak
Guillaume Huertas
Albert Nguyen Van Nhien
Frédéric Sauvage
author_sort Iryna Sagaidak
collection DOAJ
description A novel family of iodide salts and ionic liquids based on different carbohydrate core units is herein described for application in dye-sensitized solar cell (DSC). The influence of the molecular skeleton and the cationic structure on the electrolyte properties, device performance and on interfacial charge transfer has been investigated. In combination with the C106 polypyridyl ruthenium sensitizer, power conversion efficiencies lying between 5.0% and 7.3% under standard Air Mass (A.M.) 1.5G conditions were obtained in association with a low volatile methoxypropionitrile (MPN)-based electrolyte.
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spelling doaj.art-303eadbb853f432e977136125227e62b2022-12-22T03:59:07ZengMDPI AGEnergies1996-10732016-03-019424110.3390/en9040241en9040241Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar CellsIryna Sagaidak0Guillaume Huertas1Albert Nguyen Van Nhien2Frédéric Sauvage3Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 7314, 33 rue Saint Leu, Amiens 80039, FranceLaboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 7314, 33 rue Saint Leu, Amiens 80039, FranceLaboratoire de Glycochimie, des Antimicrobiens et des Agroressources, Université de Picardie Jules Verne, CNRS FRE3517, 33 rue Saint Leu, Amiens 80039, FranceLaboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 7314, 33 rue Saint Leu, Amiens 80039, FranceA novel family of iodide salts and ionic liquids based on different carbohydrate core units is herein described for application in dye-sensitized solar cell (DSC). The influence of the molecular skeleton and the cationic structure on the electrolyte properties, device performance and on interfacial charge transfer has been investigated. In combination with the C106 polypyridyl ruthenium sensitizer, power conversion efficiencies lying between 5.0% and 7.3% under standard Air Mass (A.M.) 1.5G conditions were obtained in association with a low volatile methoxypropionitrile (MPN)-based electrolyte.http://www.mdpi.com/1996-1073/9/4/241dye-sensitized solar cells (DSC)ionic liquidssugar-based iodide sourcesliquid electrolyte
spellingShingle Iryna Sagaidak
Guillaume Huertas
Albert Nguyen Van Nhien
Frédéric Sauvage
Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
Energies
dye-sensitized solar cells (DSC)
ionic liquids
sugar-based iodide sources
liquid electrolyte
title Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
title_full Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
title_fullStr Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
title_full_unstemmed Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
title_short Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells
title_sort towards renewable iodide sources for electrolytes in dye sensitized solar cells
topic dye-sensitized solar cells (DSC)
ionic liquids
sugar-based iodide sources
liquid electrolyte
url http://www.mdpi.com/1996-1073/9/4/241
work_keys_str_mv AT irynasagaidak towardsrenewableiodidesourcesforelectrolytesindyesensitizedsolarcells
AT guillaumehuertas towardsrenewableiodidesourcesforelectrolytesindyesensitizedsolarcells
AT albertnguyenvannhien towardsrenewableiodidesourcesforelectrolytesindyesensitizedsolarcells
AT fredericsauvage towardsrenewableiodidesourcesforelectrolytesindyesensitizedsolarcells