Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
In the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811053414 |
| _version_ | 1818321444025663488 |
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| author | Yan Wang Jing Zhao |
| author_facet | Yan Wang Jing Zhao |
| author_sort | Yan Wang |
| collection | DOAJ |
| description | In the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups. |
| first_indexed | 2024-12-13T10:41:00Z |
| format | Article |
| id | doaj.art-30417b8c5fa04017ae7e02aa509c30d9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:41:00Z |
| publishDate | 2012-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-30417b8c5fa04017ae7e02aa509c30d92022-12-21T23:50:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m69m6910.1107/S1600536811053414Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrateYan WangJing ZhaoIn the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups.http://scripts.iucr.org/cgi-bin/paper?S1600536811053414 |
| spellingShingle | Yan Wang Jing Zhao Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate Acta Crystallographica Section E |
| title | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate |
| title_full | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate |
| title_fullStr | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate |
| title_full_unstemmed | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate |
| title_short | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate |
| title_sort | diaquabis 5 methyl 1 2 oxazole 3 carboxylato amp 954 2n o3 cobalt ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811053414 |
| work_keys_str_mv | AT yanwang diaquabis5methyl12oxazole3carboxylatoamp9542no3cobaltiidihydrate AT jingzhao diaquabis5methyl12oxazole3carboxylatoamp9542no3cobaltiidihydrate |