Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)

ABSTRACT: Electrokinetic flow phenomena are ubiquitous in electrical systems for desalination, chemical conversion, or mixing at a micro-scale. However, the important features of resulting 3D flow fields are only accessible through cost-intensive numerical simulations. Experimental 2D recording of t...

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Main Authors: Felix Stockmeier, Michael Schatz, Malte Habermann, John Linkhorst, Ali Mani, Matthias Wessling
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:MethodsX
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2215016122001947
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author Felix Stockmeier
Michael Schatz
Malte Habermann
John Linkhorst
Ali Mani
Matthias Wessling
author_facet Felix Stockmeier
Michael Schatz
Malte Habermann
John Linkhorst
Ali Mani
Matthias Wessling
author_sort Felix Stockmeier
collection DOAJ
description ABSTRACT: Electrokinetic flow phenomena are ubiquitous in electrical systems for desalination, chemical conversion, or mixing at a micro-scale. However, the important features of resulting 3D flow fields are only accessible through cost-intensive numerical simulations. Experimental 2D recording of the chaotic three-dimensional velocity fields developing for example at currents exceeding the limiting current density does not capture the complex 3D structures present in such flow fields. Additionally, numerical 3D studies are limited to dimensions three orders of magnitude smaller as found in real applications and only short run times due to the enormous computational effort. To apply the theoretical knowledge in real-world systems and create the possibility for detailed parameter studies, we present the first experimental method for recording and quantifying the time-resolved velocity field in an electrochemical microfluidic cell in 3D with dimensions found in industrial applications. We utilize this method in a co-submitted paper to record the 3D velocity field of electroconvection at a cation-exchange membrane. • Cell design suitable for simultaneous electrochemical experiments with optical 3D velocity quantification • Method optimized for velocity reconstruction of membrane-to-membrane distances found in industrial cells • Highly adaptable cell design, for optical characterization of electrochemical systems
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spelling doaj.art-305b984853f9491dafa655d33a0a34b32022-12-22T04:40:26ZengElsevierMethodsX2215-01612022-01-019101814Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)Felix Stockmeier0Michael Schatz1Malte Habermann2John Linkhorst3Ali Mani4Matthias Wessling5Chemical Process Engineering AVT.CVT, RWTH Aachen University, Germany; DWI - Leibniz-Institute for Interactive Materials, GermanyChemical Process Engineering AVT.CVT, RWTH Aachen University, Germany; DWI - Leibniz-Institute for Interactive Materials, GermanyChemical Process Engineering AVT.CVT, RWTH Aachen University, Germany; DWI - Leibniz-Institute for Interactive Materials, GermanyChemical Process Engineering AVT.CVT, RWTH Aachen University, GermanyDepartment of Mechanical Engineering, Stanford University, GermanyChemical Process Engineering AVT.CVT, RWTH Aachen University, Germany; DWI - Leibniz-Institute for Interactive Materials, Germany; Corresponding author.ABSTRACT: Electrokinetic flow phenomena are ubiquitous in electrical systems for desalination, chemical conversion, or mixing at a micro-scale. However, the important features of resulting 3D flow fields are only accessible through cost-intensive numerical simulations. Experimental 2D recording of the chaotic three-dimensional velocity fields developing for example at currents exceeding the limiting current density does not capture the complex 3D structures present in such flow fields. Additionally, numerical 3D studies are limited to dimensions three orders of magnitude smaller as found in real applications and only short run times due to the enormous computational effort. To apply the theoretical knowledge in real-world systems and create the possibility for detailed parameter studies, we present the first experimental method for recording and quantifying the time-resolved velocity field in an electrochemical microfluidic cell in 3D with dimensions found in industrial applications. We utilize this method in a co-submitted paper to record the 3D velocity field of electroconvection at a cation-exchange membrane. • Cell design suitable for simultaneous electrochemical experiments with optical 3D velocity quantification • Method optimized for velocity reconstruction of membrane-to-membrane distances found in industrial cells • Highly adaptable cell design, for optical characterization of electrochemical systemshttp://www.sciencedirect.com/science/article/pii/S2215016122001947Particle tracking velocimetry for electrokinetic flows
spellingShingle Felix Stockmeier
Michael Schatz
Malte Habermann
John Linkhorst
Ali Mani
Matthias Wessling
Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
MethodsX
Particle tracking velocimetry for electrokinetic flows
title Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
title_full Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
title_fullStr Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
title_full_unstemmed Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
title_short Measurement of Electrokinetically induced hydrodynamics at Ion-selective interfaces using 3D Micro particle tracking velocimetry (µPTV)
title_sort measurement of electrokinetically induced hydrodynamics at ion selective interfaces using 3d micro particle tracking velocimetry µptv
topic Particle tracking velocimetry for electrokinetic flows
url http://www.sciencedirect.com/science/article/pii/S2215016122001947
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