Removal of crystal violet from aquatic environment by surfactant-modified dolomite

This paper presents the adsorption of crystal violet (CV+) from aqueous solution on surfactant-modified dolomite. Liquid phase batch operations were carried out to observe the effect of various experimental parameters such as initial dye concentration, adsorbent dosage, pH and NaCl concentration. Th...

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Main Authors: Maryam Arabpour, Ahmad Rahbar-Kelishami, Reza Norouzbeigi
Format: Article
Language:English
Published: Iranian Research Organization for Science and Technology (IROST) 2016-09-01
Series:Journal of Particle Science and Technology
Subjects:
Online Access:http://jpst.irost.ir/article_492_a7daf6809459a91c09101b92d2462ab7.pdf
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author Maryam Arabpour
Ahmad Rahbar-Kelishami
Reza Norouzbeigi
author_facet Maryam Arabpour
Ahmad Rahbar-Kelishami
Reza Norouzbeigi
author_sort Maryam Arabpour
collection DOAJ
description This paper presents the adsorption of crystal violet (CV+) from aqueous solution on surfactant-modified dolomite. Liquid phase batch operations were carried out to observe the effect of various experimental parameters such as initial dye concentration, adsorbent dosage, pH and NaCl concentration. The optimum conditions for these parameters were calculated by Taguchi method. Equilibrium isotherm data were analyzed according to Langmuir, Freundlich and Temkin equations. The experimental data fitted well to Freundlich adsorption model. The maximum adsorption capacities by Langmuir analysis were determined to be 49.261mg/g at 22℃ that indicates suitable performance by of this adsorbent. The pPseudo-first-order and, pseudo-second-order kinetics and the intraparticle diffusion models were also evaluated for the adsorption of CV+ onto surfactant-modified dolomite. The positive value of free energy change confirmed the nature of physisorption of dye onto adsorbent.
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spelling doaj.art-309fcd4a1076434994995781bfbc73922022-12-21T23:21:26ZengIranian Research Organization for Science and Technology (IROST)Journal of Particle Science and Technology2423-40872423-40792016-09-012317318210.22104/jpst.2017.492492Removal of crystal violet from aquatic environment by surfactant-modified dolomiteMaryam Arabpour0Ahmad Rahbar-Kelishami1Reza Norouzbeigi2Department of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, IranDepartment of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, IranDepartment of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, IranThis paper presents the adsorption of crystal violet (CV+) from aqueous solution on surfactant-modified dolomite. Liquid phase batch operations were carried out to observe the effect of various experimental parameters such as initial dye concentration, adsorbent dosage, pH and NaCl concentration. The optimum conditions for these parameters were calculated by Taguchi method. Equilibrium isotherm data were analyzed according to Langmuir, Freundlich and Temkin equations. The experimental data fitted well to Freundlich adsorption model. The maximum adsorption capacities by Langmuir analysis were determined to be 49.261mg/g at 22℃ that indicates suitable performance by of this adsorbent. The pPseudo-first-order and, pseudo-second-order kinetics and the intraparticle diffusion models were also evaluated for the adsorption of CV+ onto surfactant-modified dolomite. The positive value of free energy change confirmed the nature of physisorption of dye onto adsorbent.http://jpst.irost.ir/article_492_a7daf6809459a91c09101b92d2462ab7.pdfAdsorptionCrystal violet (CV+)KineticsSurfactant-modified dolomiteTaguchi method
spellingShingle Maryam Arabpour
Ahmad Rahbar-Kelishami
Reza Norouzbeigi
Removal of crystal violet from aquatic environment by surfactant-modified dolomite
Journal of Particle Science and Technology
Adsorption
Crystal violet (CV+)
Kinetics
Surfactant-modified dolomite
Taguchi method
title Removal of crystal violet from aquatic environment by surfactant-modified dolomite
title_full Removal of crystal violet from aquatic environment by surfactant-modified dolomite
title_fullStr Removal of crystal violet from aquatic environment by surfactant-modified dolomite
title_full_unstemmed Removal of crystal violet from aquatic environment by surfactant-modified dolomite
title_short Removal of crystal violet from aquatic environment by surfactant-modified dolomite
title_sort removal of crystal violet from aquatic environment by surfactant modified dolomite
topic Adsorption
Crystal violet (CV+)
Kinetics
Surfactant-modified dolomite
Taguchi method
url http://jpst.irost.ir/article_492_a7daf6809459a91c09101b92d2462ab7.pdf
work_keys_str_mv AT maryamarabpour removalofcrystalvioletfromaquaticenvironmentbysurfactantmodifieddolomite
AT ahmadrahbarkelishami removalofcrystalvioletfromaquaticenvironmentbysurfactantmodifieddolomite
AT rezanorouzbeigi removalofcrystalvioletfromaquaticenvironmentbysurfactantmodifieddolomite