Crystal structure of poly[[diaquatetra-μ2-cyanido-platinum(II)iron(II)] methanol 4/3-solvate]: a three-dimensional Hofmann clathrate analogue

Crystal structure of poly[[diaquatetra-μ2-cyanido-platinum(II)iron(II)] methanol 4/3-solvate]: a three-dimensional Hofmann clathrate analogue

In the title polymeric coordination compound, {[FePt(CN)4(H2O)2]·1.33CH3OH}n, the FeII cation (site symmetry 4/mm.m) is coordinated by the N atoms of four cyanide anions (CN−) and the O atoms of two water molecules, forming a nearly regular [FeN4O2] octahedron. According the Fe—N and Fe—O bond lengt...

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Bibliographic Details
Main Authors: Volodymyr M. Hiiuk, Vasyl Mykhailovych, Sergiu Shova, Irina A. Golenya, Il'ya A. Gural'skiy
Format: Article
Language:English
Published: International Union of Crystallography 2022-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
coordination compounds
iron(ii)
clathrate
platinum
cyanido ligand
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022000573

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