Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film
Poly 1-amino-9, 10-anthraquinone (PAAQ) films were prepared by the electropolymerization of 1-amino-9,10-anthraquinone (AAQ) on platinum substrate from aqueous media, where 5.0 × 10−3 mol L−1 AAQ and 6.0 mol L−1 H2SO4 were used. The kinetics of the electropolymerization process was investigated by d...
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| Format: | Article |
| Language: | English |
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Elsevier
2012-07-01
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| Series: | Journal of Advanced Research |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2090123211001007 |
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| author | Shymaa S. Medany Khaled M. Ismail Waheed A. Badawy |
| author_facet | Shymaa S. Medany Khaled M. Ismail Waheed A. Badawy |
| author_sort | Shymaa S. Medany |
| collection | DOAJ |
| description | Poly 1-amino-9, 10-anthraquinone (PAAQ) films were prepared by the electropolymerization of 1-amino-9,10-anthraquinone (AAQ) on platinum substrate from aqueous media, where 5.0 × 10−3 mol L−1 AAQ and 6.0 mol L−1 H2SO4 were used. The kinetics of the electropolymerization process was investigated by determining the change of the charge consumed during the polymerization process with time at different concentrations of both monomer and electrolyte. The results have shown that the process follows first order kinetics with respect to the monomer concentration. The order of the reaction with respect to the aqueous solvent i.e. H2SO4 was found to be negative. The polymer films were successfully used as sensors for the electroanalytical determination of many hazardous compounds, e.g. phenols, and biologically important materials like dopamine. The electroanalytical determination was based on the measurements of the oxidation current peak of the material in the cyclic voltammetric measurements. The cyclic voltammograms were recorded at a scan rate of 100 mV s−1 and different analyte concentrations. A calibration curve was constructed for each analyte, from which the determination of low concentrations of catechol and hydroquinone (HQ) as examples of hazardous compounds present in waste water and also for ascorbic acid and dopamine as examples of valuable biological materials can be achieved. |
| first_indexed | 2024-12-10T11:38:14Z |
| format | Article |
| id | doaj.art-30ac5dd400524aa8aea2a857c558dba1 |
| institution | Directory Open Access Journal |
| issn | 2090-1232 2090-1224 |
| language | English |
| last_indexed | 2024-12-10T11:38:14Z |
| publishDate | 2012-07-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Advanced Research |
| spelling | doaj.art-30ac5dd400524aa8aea2a857c558dba12022-12-22T01:50:21ZengElsevierJournal of Advanced Research2090-12322090-12242012-07-013326126810.1016/j.jare.2011.09.001Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer filmShymaa S. MedanyKhaled M. IsmailWaheed A. BadawyPoly 1-amino-9, 10-anthraquinone (PAAQ) films were prepared by the electropolymerization of 1-amino-9,10-anthraquinone (AAQ) on platinum substrate from aqueous media, where 5.0 × 10−3 mol L−1 AAQ and 6.0 mol L−1 H2SO4 were used. The kinetics of the electropolymerization process was investigated by determining the change of the charge consumed during the polymerization process with time at different concentrations of both monomer and electrolyte. The results have shown that the process follows first order kinetics with respect to the monomer concentration. The order of the reaction with respect to the aqueous solvent i.e. H2SO4 was found to be negative. The polymer films were successfully used as sensors for the electroanalytical determination of many hazardous compounds, e.g. phenols, and biologically important materials like dopamine. The electroanalytical determination was based on the measurements of the oxidation current peak of the material in the cyclic voltammetric measurements. The cyclic voltammograms were recorded at a scan rate of 100 mV s−1 and different analyte concentrations. A calibration curve was constructed for each analyte, from which the determination of low concentrations of catechol and hydroquinone (HQ) as examples of hazardous compounds present in waste water and also for ascorbic acid and dopamine as examples of valuable biological materials can be achieved.http://www.sciencedirect.com/science/article/pii/S2090123211001007Ascorbic acidCatecholDopamineHydroquinonePolyaminoanthraquinone |
| spellingShingle | Shymaa S. Medany Khaled M. Ismail Waheed A. Badawy Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film Journal of Advanced Research Ascorbic acid Catechol Dopamine Hydroquinone Polyaminoanthraquinone |
| title | Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| title_full | Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| title_fullStr | Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| title_full_unstemmed | Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| title_short | Kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| title_sort | kinetics of the electropolymerization of aminoanthraquinone from aqueous solutions and analytical applications of the polymer film |
| topic | Ascorbic acid Catechol Dopamine Hydroquinone Polyaminoanthraquinone |
| url | http://www.sciencedirect.com/science/article/pii/S2090123211001007 |
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