Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents

Modern electronic information technology has led social life into inevitable electromagnetic pollution, making microwave absorbing materials more and more important. Herein, dielectric-conductive ZnO/C hybrid composite absorbents were prepared by two-step carbonization with ZnO powders and glucose a...

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Main Authors: Junxiao Yan, Hongyao Jia, Liang Zhou, Zhenjun Wang, Hongbo Wang
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/7/1220
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author Junxiao Yan
Hongyao Jia
Liang Zhou
Zhenjun Wang
Hongbo Wang
author_facet Junxiao Yan
Hongyao Jia
Liang Zhou
Zhenjun Wang
Hongbo Wang
author_sort Junxiao Yan
collection DOAJ
description Modern electronic information technology has led social life into inevitable electromagnetic pollution, making microwave absorbing materials more and more important. Herein, dielectric-conductive ZnO/C hybrid composite absorbents were prepared by two-step carbonization with ZnO powders and glucose as critical materials. The electrical conductivity, complex permittivity, and reflection loss were analyzed to study the dielectric and microwave absorption properties. Results show that the prepared ZnO/C composite absorbents exist in the form of rod-like ZnO dispersed in the irregular block carbon, and the complex permittivity of the composite absorbents can be adjusted via varying the carbonization temperature. The minimum reflection loss of −25.64 dB is achieved at 1.8 mm thickness for the composite absorbent with 50 wt.% absorbent content as the final carbonization temperature is 750 °C, and the optimum effective absorption bandwidth is 2.21 GHz at 9.64–11.85 GHz. The excellent microwave absorption properties of ZnO/C composite absorbents are attributed to the combination actions of dipole polarization, conductance loss, and interface polarization, which is significant for the purposeful design of superior microwave-absorbing materials with dielectric and conductive absorbents.
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spelling doaj.art-30b0dce0a5a5456baeb8c9bd7ba1c9dd2023-11-18T20:29:37ZengMDPI AGMetals2075-47012023-07-01137122010.3390/met13071220Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite AbsorbentsJunxiao Yan0Hongyao Jia1Liang Zhou2Zhenjun Wang3Hongbo Wang4School of Materials Science and Engineering, Chang’an University, Xi’an 710064, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710064, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710064, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710064, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710064, ChinaModern electronic information technology has led social life into inevitable electromagnetic pollution, making microwave absorbing materials more and more important. Herein, dielectric-conductive ZnO/C hybrid composite absorbents were prepared by two-step carbonization with ZnO powders and glucose as critical materials. The electrical conductivity, complex permittivity, and reflection loss were analyzed to study the dielectric and microwave absorption properties. Results show that the prepared ZnO/C composite absorbents exist in the form of rod-like ZnO dispersed in the irregular block carbon, and the complex permittivity of the composite absorbents can be adjusted via varying the carbonization temperature. The minimum reflection loss of −25.64 dB is achieved at 1.8 mm thickness for the composite absorbent with 50 wt.% absorbent content as the final carbonization temperature is 750 °C, and the optimum effective absorption bandwidth is 2.21 GHz at 9.64–11.85 GHz. The excellent microwave absorption properties of ZnO/C composite absorbents are attributed to the combination actions of dipole polarization, conductance loss, and interface polarization, which is significant for the purposeful design of superior microwave-absorbing materials with dielectric and conductive absorbents.https://www.mdpi.com/2075-4701/13/7/1220carbonizationcomplex permittivitydielectric-conductive couplingmicrowave absorptionZnO/C absorbents
spellingShingle Junxiao Yan
Hongyao Jia
Liang Zhou
Zhenjun Wang
Hongbo Wang
Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
Metals
carbonization
complex permittivity
dielectric-conductive coupling
microwave absorption
ZnO/C absorbents
title Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
title_full Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
title_fullStr Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
title_full_unstemmed Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
title_short Tunable Complex Permittivity and Strong Microwave Absorption Properties of Novel Dielectric-Conductive ZnO/C Hybrid Composite Absorbents
title_sort tunable complex permittivity and strong microwave absorption properties of novel dielectric conductive zno c hybrid composite absorbents
topic carbonization
complex permittivity
dielectric-conductive coupling
microwave absorption
ZnO/C absorbents
url https://www.mdpi.com/2075-4701/13/7/1220
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