Heat of hydration in clays stabilized by a high-alumina steel furnace slag

This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ran...

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Main Authors: Thien Q. Tran, Amir Behravan, Alexander S. Brand
Format: Article
Language:English
Published: Elsevier 2022-09-01
Series:Cleaner Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S277239762200065X
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author Thien Q. Tran
Amir Behravan
Alexander S. Brand
author_facet Thien Q. Tran
Amir Behravan
Alexander S. Brand
author_sort Thien Q. Tran
collection DOAJ
description This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ranging from 1.0 to 1.5. The hydration properties of stabilized mixtures using lime (CaO) or portland cement (PC) were also tested for comparison at the same experimental conditions. The obtained thermal power and total heat curves of stabilized mixtures could contribute to confirming that there is a hydration process taking place in clay stabilized by SFS. Relative to lime and PC, the SFS performed similarly in terms of hydration heat behavior. When blended into clays, SFS provided a more significant hydration heat behavior than cement, but that was much milder than lime. X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also employed to qualitatively analyze the mineralogy of the stabilized mixtures.
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spelling doaj.art-30beed09161f44c798d95d42d55398282022-12-22T03:13:07ZengElsevierCleaner Materials2772-39762022-09-015100105Heat of hydration in clays stabilized by a high-alumina steel furnace slagThien Q. Tran0Amir Behravan1Alexander S. Brand2The Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USAThe Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USAThe Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA; Department of Materials Science and Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA; Corresponding author at: The Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA.This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ranging from 1.0 to 1.5. The hydration properties of stabilized mixtures using lime (CaO) or portland cement (PC) were also tested for comparison at the same experimental conditions. The obtained thermal power and total heat curves of stabilized mixtures could contribute to confirming that there is a hydration process taking place in clay stabilized by SFS. Relative to lime and PC, the SFS performed similarly in terms of hydration heat behavior. When blended into clays, SFS provided a more significant hydration heat behavior than cement, but that was much milder than lime. X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also employed to qualitatively analyze the mineralogy of the stabilized mixtures.http://www.sciencedirect.com/science/article/pii/S277239762200065XSteel furnace slag (SFS)KaolinBentoniteisothermal calorimetry (IC)X-ray diffraction (XRD)thermogravimetric analysis (TGA)
spellingShingle Thien Q. Tran
Amir Behravan
Alexander S. Brand
Heat of hydration in clays stabilized by a high-alumina steel furnace slag
Cleaner Materials
Steel furnace slag (SFS)
Kaolin
Bentonite
isothermal calorimetry (IC)
X-ray diffraction (XRD)
thermogravimetric analysis (TGA)
title Heat of hydration in clays stabilized by a high-alumina steel furnace slag
title_full Heat of hydration in clays stabilized by a high-alumina steel furnace slag
title_fullStr Heat of hydration in clays stabilized by a high-alumina steel furnace slag
title_full_unstemmed Heat of hydration in clays stabilized by a high-alumina steel furnace slag
title_short Heat of hydration in clays stabilized by a high-alumina steel furnace slag
title_sort heat of hydration in clays stabilized by a high alumina steel furnace slag
topic Steel furnace slag (SFS)
Kaolin
Bentonite
isothermal calorimetry (IC)
X-ray diffraction (XRD)
thermogravimetric analysis (TGA)
url http://www.sciencedirect.com/science/article/pii/S277239762200065X
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