Heat of hydration in clays stabilized by a high-alumina steel furnace slag
This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ran...
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Format: | Article |
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Elsevier
2022-09-01
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Series: | Cleaner Materials |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S277239762200065X |
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author | Thien Q. Tran Amir Behravan Alexander S. Brand |
author_facet | Thien Q. Tran Amir Behravan Alexander S. Brand |
author_sort | Thien Q. Tran |
collection | DOAJ |
description | This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ranging from 1.0 to 1.5. The hydration properties of stabilized mixtures using lime (CaO) or portland cement (PC) were also tested for comparison at the same experimental conditions. The obtained thermal power and total heat curves of stabilized mixtures could contribute to confirming that there is a hydration process taking place in clay stabilized by SFS. Relative to lime and PC, the SFS performed similarly in terms of hydration heat behavior. When blended into clays, SFS provided a more significant hydration heat behavior than cement, but that was much milder than lime. X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also employed to qualitatively analyze the mineralogy of the stabilized mixtures. |
first_indexed | 2024-04-12T22:58:50Z |
format | Article |
id | doaj.art-30beed09161f44c798d95d42d5539828 |
institution | Directory Open Access Journal |
issn | 2772-3976 |
language | English |
last_indexed | 2024-04-12T22:58:50Z |
publishDate | 2022-09-01 |
publisher | Elsevier |
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series | Cleaner Materials |
spelling | doaj.art-30beed09161f44c798d95d42d55398282022-12-22T03:13:07ZengElsevierCleaner Materials2772-39762022-09-015100105Heat of hydration in clays stabilized by a high-alumina steel furnace slagThien Q. Tran0Amir Behravan1Alexander S. Brand2The Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USAThe Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USAThe Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA; Department of Materials Science and Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA; Corresponding author at: The Charles Edward Via, Jr. Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24060, USA.This investigation utilized isothermal calorimetry (IC) to quantify the heat of hydration of steel furnace slag (SFS)-stabilized clays to assess the chemical aspects of the stabilization. Specifically, kaolin and bentonite clays were each blended with 40% of SFS by mass at water-to-binder ratios ranging from 1.0 to 1.5. The hydration properties of stabilized mixtures using lime (CaO) or portland cement (PC) were also tested for comparison at the same experimental conditions. The obtained thermal power and total heat curves of stabilized mixtures could contribute to confirming that there is a hydration process taking place in clay stabilized by SFS. Relative to lime and PC, the SFS performed similarly in terms of hydration heat behavior. When blended into clays, SFS provided a more significant hydration heat behavior than cement, but that was much milder than lime. X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also employed to qualitatively analyze the mineralogy of the stabilized mixtures.http://www.sciencedirect.com/science/article/pii/S277239762200065XSteel furnace slag (SFS)KaolinBentoniteisothermal calorimetry (IC)X-ray diffraction (XRD)thermogravimetric analysis (TGA) |
spellingShingle | Thien Q. Tran Amir Behravan Alexander S. Brand Heat of hydration in clays stabilized by a high-alumina steel furnace slag Cleaner Materials Steel furnace slag (SFS) Kaolin Bentonite isothermal calorimetry (IC) X-ray diffraction (XRD) thermogravimetric analysis (TGA) |
title | Heat of hydration in clays stabilized by a high-alumina steel furnace slag |
title_full | Heat of hydration in clays stabilized by a high-alumina steel furnace slag |
title_fullStr | Heat of hydration in clays stabilized by a high-alumina steel furnace slag |
title_full_unstemmed | Heat of hydration in clays stabilized by a high-alumina steel furnace slag |
title_short | Heat of hydration in clays stabilized by a high-alumina steel furnace slag |
title_sort | heat of hydration in clays stabilized by a high alumina steel furnace slag |
topic | Steel furnace slag (SFS) Kaolin Bentonite isothermal calorimetry (IC) X-ray diffraction (XRD) thermogravimetric analysis (TGA) |
url | http://www.sciencedirect.com/science/article/pii/S277239762200065X |
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