Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
The coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines ca...
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-01-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/20/2/1755 |
| _version_ | 1829532744203370496 |
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| author | Eswararao Doni Shengze Zhou John A. Murphy |
| author_facet | Eswararao Doni Shengze Zhou John A. Murphy |
| author_sort | Eswararao Doni |
| collection | DOAJ |
| description | The coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines can lead to either 1,1,2-triarylethenes or 1,1,2-triarylethanes, depending on the conditions used. |
| first_indexed | 2024-12-16T18:45:05Z |
| format | Article |
| id | doaj.art-30bfc32291a7409d81f194dc3b6afc7e |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-16T18:45:05Z |
| publishDate | 2015-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-30bfc32291a7409d81f194dc3b6afc7e2022-12-21T22:20:52ZengMDPI AGMolecules1420-30492015-01-012021755177410.3390/molecules20021755molecules20021755Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-ButoxideEswararao Doni0Shengze Zhou1John A. Murphy2WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UKWestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UKWestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UKThe coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines can lead to either 1,1,2-triarylethenes or 1,1,2-triarylethanes, depending on the conditions used.http://www.mdpi.com/1420-3049/20/2/1755electron transfercouplinghaloarenespotassium tert-butoxidediketopiperazine |
| spellingShingle | Eswararao Doni Shengze Zhou John A. Murphy Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide Molecules electron transfer coupling haloarenes potassium tert-butoxide diketopiperazine |
| title | Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide |
| title_full | Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide |
| title_fullStr | Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide |
| title_full_unstemmed | Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide |
| title_short | Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide |
| title_sort | electron transfer induced coupling of haloarenes to styrenes and 1 1 diphenylethenes triggered by diketopiperazines and potassium tert butoxide |
| topic | electron transfer coupling haloarenes potassium tert-butoxide diketopiperazine |
| url | http://www.mdpi.com/1420-3049/20/2/1755 |
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