Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution
Novel methodologies for cleaving inherently inert C(sp 2)‒ C(sp 2) bonds are desirable. Here, the authors report the use of an oriented electric field to cleave C(sp 2)‒ C(sp 2) in cycloparaphenylenes via electrophilic aromatic substitution.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2023-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35686-4 |
| _version_ | 1797945793040089088 |
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| author | Junfeng Lin Yaxin Lv Kai Song Xuwei Song Hongjun Zang Pingwu Du Yaping Zang Daoben Zhu |
| author_facet | Junfeng Lin Yaxin Lv Kai Song Xuwei Song Hongjun Zang Pingwu Du Yaping Zang Daoben Zhu |
| author_sort | Junfeng Lin |
| collection | DOAJ |
| description | Novel methodologies for cleaving inherently inert C(sp 2)‒ C(sp 2) bonds are desirable. Here, the authors report the use of an oriented electric field to cleave C(sp 2)‒ C(sp 2) in cycloparaphenylenes via electrophilic aromatic substitution. |
| first_indexed | 2024-04-10T21:00:45Z |
| format | Article |
| id | doaj.art-30cc628b8e4f4e72b766c4fe57b3c147 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-10T21:00:45Z |
| publishDate | 2023-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-30cc628b8e4f4e72b766c4fe57b3c1472023-01-22T12:18:22ZengNature PortfolioNature Communications2041-17232023-01-011411710.1038/s41467-022-35686-4Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitutionJunfeng Lin0Yaxin Lv1Kai Song2Xuwei Song3Hongjun Zang4Pingwu Du5Yaping Zang6Daoben Zhu7Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesSchool of Chemistry, Tiangong UniversityHefei National Research Center for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of ChinaBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of SciencesNovel methodologies for cleaving inherently inert C(sp 2)‒ C(sp 2) bonds are desirable. Here, the authors report the use of an oriented electric field to cleave C(sp 2)‒ C(sp 2) in cycloparaphenylenes via electrophilic aromatic substitution.https://doi.org/10.1038/s41467-022-35686-4 |
| spellingShingle | Junfeng Lin Yaxin Lv Kai Song Xuwei Song Hongjun Zang Pingwu Du Yaping Zang Daoben Zhu Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution Nature Communications |
| title | Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution |
| title_full | Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution |
| title_fullStr | Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution |
| title_full_unstemmed | Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution |
| title_short | Cleavage of non-polar C(sp 2)‒C(sp 2) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution |
| title_sort | cleavage of non polar c sp 2 c sp 2 bonds in cycloparaphenylenes via electric field catalyzed electrophilic aromatic substitution |
| url | https://doi.org/10.1038/s41467-022-35686-4 |
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