Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays

Abstract The formation of well‐defined, functional surfaces that incorporate the unique properties of inorganic nanoparticles (NPs) requires robust and scalable fabrication strategies. Herein, we report a methodology for the decoration of polymer molds with plasmonic (gold) nanoparticle arrays. Wrin...

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Main Authors: Ruosong Wang, Philipp Zimmermann, Daniel Schletz, Marisa Hoffmann, Patrick Probst, Andreas Fery, Jürgen Nagel, Christian Rossner
Format: Article
Language:English
Published: Wiley-VCH 2022-11-01
Series:Nano Select
Subjects:
Online Access:https://doi.org/10.1002/nano.202200110
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author Ruosong Wang
Philipp Zimmermann
Daniel Schletz
Marisa Hoffmann
Patrick Probst
Andreas Fery
Jürgen Nagel
Christian Rossner
author_facet Ruosong Wang
Philipp Zimmermann
Daniel Schletz
Marisa Hoffmann
Patrick Probst
Andreas Fery
Jürgen Nagel
Christian Rossner
author_sort Ruosong Wang
collection DOAJ
description Abstract The formation of well‐defined, functional surfaces that incorporate the unique properties of inorganic nanoparticles (NPs) requires robust and scalable fabrication strategies. Herein, we report a methodology for the decoration of polymer molds with plasmonic (gold) nanoparticle arrays. Wrinkled soft templates were used to assemble gold NPs (74 nm) into line arrays. These pre‐formed nanoparticle arrays were transferred in a subsequent step onto polycarbonate molds via an injection molding process. Scanning electron microscopy analysis revealed the structural fidelity of the pattern structure upon transfer. The preservation of the optical functionality of the gold nanoparticle line arrays was proven by surface‐enhanced Raman scattering (SERS) experiments. The reported strategy of nanoparticle pattern transfer to polymer bodies by this robust process is expected to prove useful for the fabrication of polymer surfaces with tailored optical functionality.
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spelling doaj.art-30defd0f8e794796b86ea52d16c6d6762022-12-22T04:37:36ZengWiley-VCHNano Select2688-40112022-11-013111502150810.1002/nano.202200110Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arraysRuosong Wang0Philipp Zimmermann1Daniel Schletz2Marisa Hoffmann3Patrick Probst4Andreas Fery5Jürgen Nagel6Christian Rossner7Leibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Polymerwerkstoffe Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Polymerwerkstoffe Hohe Straße 6 Dresden GermanyLeibniz‐Institut für Polymerforschung Dresden e.V. Institut für Physikalische Chemie und Physik der Polymere Hohe Straße 6 Dresden GermanyAbstract The formation of well‐defined, functional surfaces that incorporate the unique properties of inorganic nanoparticles (NPs) requires robust and scalable fabrication strategies. Herein, we report a methodology for the decoration of polymer molds with plasmonic (gold) nanoparticle arrays. Wrinkled soft templates were used to assemble gold NPs (74 nm) into line arrays. These pre‐formed nanoparticle arrays were transferred in a subsequent step onto polycarbonate molds via an injection molding process. Scanning electron microscopy analysis revealed the structural fidelity of the pattern structure upon transfer. The preservation of the optical functionality of the gold nanoparticle line arrays was proven by surface‐enhanced Raman scattering (SERS) experiments. The reported strategy of nanoparticle pattern transfer to polymer bodies by this robust process is expected to prove useful for the fabrication of polymer surfaces with tailored optical functionality.https://doi.org/10.1002/nano.202200110injection moldingnanopatterned polymer surfacesplasmonic nanoparticlessurface‐enhanced Raman scatteringtemplate‐assisted assembly
spellingShingle Ruosong Wang
Philipp Zimmermann
Daniel Schletz
Marisa Hoffmann
Patrick Probst
Andreas Fery
Jürgen Nagel
Christian Rossner
Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
Nano Select
injection molding
nanopatterned polymer surfaces
plasmonic nanoparticles
surface‐enhanced Raman scattering
template‐assisted assembly
title Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
title_full Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
title_fullStr Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
title_full_unstemmed Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
title_short Nano meets macro: Furnishing the surface of polymer molds with gold‐nanoparticle arrays
title_sort nano meets macro furnishing the surface of polymer molds with gold nanoparticle arrays
topic injection molding
nanopatterned polymer surfaces
plasmonic nanoparticles
surface‐enhanced Raman scattering
template‐assisted assembly
url https://doi.org/10.1002/nano.202200110
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