Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

Various kinds of monocrystalline coordination polymers are available thanks to the rapid development of related synthetic strategies. The intrinsic properties of coordination polymers have been carefully investigated on the basis of the available monocrystalline samples. Regarding the great potentia...

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Main Authors: Lingling Xia, Qinyue Wang, Ming Hu
Format: Article
Language:English
Published: Beilstein-Institut 2022-08-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.13.67
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author Lingling Xia
Qinyue Wang
Ming Hu
author_facet Lingling Xia
Qinyue Wang
Ming Hu
author_sort Lingling Xia
collection DOAJ
description Various kinds of monocrystalline coordination polymers are available thanks to the rapid development of related synthetic strategies. The intrinsic properties of coordination polymers have been carefully investigated on the basis of the available monocrystalline samples. Regarding the great potential of coordination polymers in various fields, it becomes important to tailor the properties of coordination polymers to meet practical requirements, which sometimes cannot be achieved through molecular/crystal engineering. Nanoarchitectonics offer unique opportunities to manipulate the properties of materials through integration of the monocrystalline building blocks with other components. Recently, nanoarchitectonics has started to play a significant role in the field of coordination polymers. In this short review, we summarize recent advances in nanoarchitectures based on monocrystalline coordination polymers that are formed through confined assembly. We first discuss the crystallization of coordination polymer single crystals inside confined liquid networks or on substrates through assembly of nodes and ligands. Then, we discuss assembly of preformed coordination polymer single crystals inside confined liquid networks or on substrates. In each part, we discuss the properties of the coordination polymer single crystals as well as their performance in energy, environmental, and biomedical applications.
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spelling doaj.art-30e8b2a5224241ffa00224172b3a585d2022-12-22T03:17:04ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862022-08-0113176377710.3762/bjnano.13.672190-4286-13-67Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assemblyLingling Xia0Qinyue Wang1Ming Hu2Engineering Research Center for Nanophotonics and Advanced Instrument (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China Engineering Research Center for Nanophotonics and Advanced Instrument (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China Engineering Research Center for Nanophotonics and Advanced Instrument (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China Various kinds of monocrystalline coordination polymers are available thanks to the rapid development of related synthetic strategies. The intrinsic properties of coordination polymers have been carefully investigated on the basis of the available monocrystalline samples. Regarding the great potential of coordination polymers in various fields, it becomes important to tailor the properties of coordination polymers to meet practical requirements, which sometimes cannot be achieved through molecular/crystal engineering. Nanoarchitectonics offer unique opportunities to manipulate the properties of materials through integration of the monocrystalline building blocks with other components. Recently, nanoarchitectonics has started to play a significant role in the field of coordination polymers. In this short review, we summarize recent advances in nanoarchitectures based on monocrystalline coordination polymers that are formed through confined assembly. We first discuss the crystallization of coordination polymer single crystals inside confined liquid networks or on substrates through assembly of nodes and ligands. Then, we discuss assembly of preformed coordination polymer single crystals inside confined liquid networks or on substrates. In each part, we discuss the properties of the coordination polymer single crystals as well as their performance in energy, environmental, and biomedical applications.https://doi.org/10.3762/bjnano.13.67applicationsassemblycoordination polymermetal-organic frameworksnanoarchitectonics
spellingShingle Lingling Xia
Qinyue Wang
Ming Hu
Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
Beilstein Journal of Nanotechnology
applications
assembly
coordination polymer
metal-organic frameworks
nanoarchitectonics
title Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
title_full Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
title_fullStr Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
title_full_unstemmed Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
title_short Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
title_sort recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly
topic applications
assembly
coordination polymer
metal-organic frameworks
nanoarchitectonics
url https://doi.org/10.3762/bjnano.13.67
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AT qinyuewang recentadvancesinnanoarchitecturesofmonocrystallinecoordinationpolymersthroughconfinedassembly
AT minghu recentadvancesinnanoarchitecturesofmonocrystallinecoordinationpolymersthroughconfinedassembly