Effects of Hydrogen on Frictional Properties of DLC Films

The tribological behavior of diamond-like carbon films (DLC) is strongly dependent on the hydrogen content, sp2/sp3 ratio, and sliding environment. Some hydrogenated amorphous carbon films (a-C:H) exhibit superlow friction in hydrogen conditions. However, previous works have not clarified the domina...

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Main Authors: Hikaru Okubo, Kenta Oshima, Ryo Tuboi, Chiharu Tadokoro, Shinya Sasaki
Format: Article
Language:English
Published: Japanese Society of Tribologists 2015-12-01
Series:Tribology Online
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/trol/10/6/10_397/_pdf/-char/en
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author Hikaru Okubo
Kenta Oshima
Ryo Tuboi
Chiharu Tadokoro
Shinya Sasaki
author_facet Hikaru Okubo
Kenta Oshima
Ryo Tuboi
Chiharu Tadokoro
Shinya Sasaki
author_sort Hikaru Okubo
collection DOAJ
description The tribological behavior of diamond-like carbon films (DLC) is strongly dependent on the hydrogen content, sp2/sp3 ratio, and sliding environment. Some hydrogenated amorphous carbon films (a-C:H) exhibit superlow friction in hydrogen conditions. However, previous works have not clarified the dominant factors of the superlow friction phenomena of DLC films. In this research, we focused on the effects of hydrogen derived from the surrounding atmosphere and the hydrogen within the DLC films on superlow friction phenomena. To investigate these effects, friction tests were conducted on three DLC films having different hydrogen contents (0, and 18, 30 at%) in the air and in low-pressure-hydrogen conditions at various hydrogen pressures. After the friction tests, the wear tracks were examined by confocal laser scanning microscopy, Raman spectroscopy, elastic recoil detection (ERDA) analysis, and time-of-flight secondary ion mass spectrometry (TOF-SIMS). The hydrogen derived from the surrounding atmosphere and the formation of the hydrogen-rich tribofilm were key factors for the superlow friction phenomena.
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spelling doaj.art-311c8283493049aea73bad1bbb355fa32022-12-21T23:13:07ZengJapanese Society of TribologistsTribology Online1881-21982015-12-0110639740310.2474/trol.10.397trolEffects of Hydrogen on Frictional Properties of DLC FilmsHikaru Okubo0Kenta Oshima1Ryo Tuboi2Chiharu Tadokoro3Shinya Sasaki4Graduate School Tokyo University of ScienceGraduate School Tokyo University of ScienceDaido University Tokyo University of Science Tokyo University of Science The tribological behavior of diamond-like carbon films (DLC) is strongly dependent on the hydrogen content, sp2/sp3 ratio, and sliding environment. Some hydrogenated amorphous carbon films (a-C:H) exhibit superlow friction in hydrogen conditions. However, previous works have not clarified the dominant factors of the superlow friction phenomena of DLC films. In this research, we focused on the effects of hydrogen derived from the surrounding atmosphere and the hydrogen within the DLC films on superlow friction phenomena. To investigate these effects, friction tests were conducted on three DLC films having different hydrogen contents (0, and 18, 30 at%) in the air and in low-pressure-hydrogen conditions at various hydrogen pressures. After the friction tests, the wear tracks were examined by confocal laser scanning microscopy, Raman spectroscopy, elastic recoil detection (ERDA) analysis, and time-of-flight secondary ion mass spectrometry (TOF-SIMS). The hydrogen derived from the surrounding atmosphere and the formation of the hydrogen-rich tribofilm were key factors for the superlow friction phenomena.https://www.jstage.jst.go.jp/article/trol/10/6/10_397/_pdf/-char/endiamond-like carbonsuperlow frictionhydrogentribologytribofilm
spellingShingle Hikaru Okubo
Kenta Oshima
Ryo Tuboi
Chiharu Tadokoro
Shinya Sasaki
Effects of Hydrogen on Frictional Properties of DLC Films
Tribology Online
diamond-like carbon
superlow friction
hydrogen
tribology
tribofilm
title Effects of Hydrogen on Frictional Properties of DLC Films
title_full Effects of Hydrogen on Frictional Properties of DLC Films
title_fullStr Effects of Hydrogen on Frictional Properties of DLC Films
title_full_unstemmed Effects of Hydrogen on Frictional Properties of DLC Films
title_short Effects of Hydrogen on Frictional Properties of DLC Films
title_sort effects of hydrogen on frictional properties of dlc films
topic diamond-like carbon
superlow friction
hydrogen
tribology
tribofilm
url https://www.jstage.jst.go.jp/article/trol/10/6/10_397/_pdf/-char/en
work_keys_str_mv AT hikaruokubo effectsofhydrogenonfrictionalpropertiesofdlcfilms
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AT chiharutadokoro effectsofhydrogenonfrictionalpropertiesofdlcfilms
AT shinyasasaki effectsofhydrogenonfrictionalpropertiesofdlcfilms