Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface

The oxidation kinetics, oxide layers composition and thicknesses of X70 steel, Y55 steel and 304 stainless steel are investigated. The results show that the oxidation rate of X70 steel increases rapidly at 1000 °C, while that of Y55 steel and 304 stainless steel increases rapidly at 1100 °C. The oxi...

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Main Authors: Siyuan Zhang, Mujun Long, Haohao Zhang, Songyuan Ai, Dengfu Chen, Peng Liu, Huamei Duan
Format: Article
Language:English
Published: Elsevier 2021-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785421001319
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author Siyuan Zhang
Mujun Long
Haohao Zhang
Songyuan Ai
Dengfu Chen
Peng Liu
Huamei Duan
author_facet Siyuan Zhang
Mujun Long
Haohao Zhang
Songyuan Ai
Dengfu Chen
Peng Liu
Huamei Duan
author_sort Siyuan Zhang
collection DOAJ
description The oxidation kinetics, oxide layers composition and thicknesses of X70 steel, Y55 steel and 304 stainless steel are investigated. The results show that the oxidation rate of X70 steel increases rapidly at 1000 °C, while that of Y55 steel and 304 stainless steel increases rapidly at 1100 °C. The oxidation kinetic coefficients of X70 steel, Y55 steel and 304 stainless steel are exp (10.7), exp (11.58) and exp (30.15), respectively, and the apparent activation energy of oxide layer are 196879.7 J/mol, 207608.1 J/mol and 469284.3 J/mol, respectively. The cross-sectional morphology and element distribution of oxide layer are obtained. With the oxidation time increases from 30min to 80 min at 1100 °C, the oxide layer thickness of X70 steel and Y55 steel increases by 1242.33 μm and 965.59 μm respectively when the weight of steels increases by 1 mg/mm2, and the oxide layer of Y55 steel is denser than that of X70 steel. A variable temperature oxidation mathematical model of the slab surface is established to predict the oxide layer thickness of slab surface.
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spelling doaj.art-31214e2fb14e4b5284b39b5de215e4ac2022-12-21T21:27:04ZengElsevierJournal of Materials Research and Technology2238-78542021-03-011120492058Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surfaceSiyuan Zhang0Mujun Long1Haohao Zhang2Songyuan Ai3Dengfu Chen4Peng Liu5Huamei Duan6Laboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaLaboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR China; Corresponding author.Laboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaLaboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaLaboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaLaboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaLaboratory of Metallurgy and Materials, College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, PR China; Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials, Chongqing University, Chongqing, 400044, PR ChinaThe oxidation kinetics, oxide layers composition and thicknesses of X70 steel, Y55 steel and 304 stainless steel are investigated. The results show that the oxidation rate of X70 steel increases rapidly at 1000 °C, while that of Y55 steel and 304 stainless steel increases rapidly at 1100 °C. The oxidation kinetic coefficients of X70 steel, Y55 steel and 304 stainless steel are exp (10.7), exp (11.58) and exp (30.15), respectively, and the apparent activation energy of oxide layer are 196879.7 J/mol, 207608.1 J/mol and 469284.3 J/mol, respectively. The cross-sectional morphology and element distribution of oxide layer are obtained. With the oxidation time increases from 30min to 80 min at 1100 °C, the oxide layer thickness of X70 steel and Y55 steel increases by 1242.33 μm and 965.59 μm respectively when the weight of steels increases by 1 mg/mm2, and the oxide layer of Y55 steel is denser than that of X70 steel. A variable temperature oxidation mathematical model of the slab surface is established to predict the oxide layer thickness of slab surface.http://www.sciencedirect.com/science/article/pii/S2238785421001319Continuous castingHot rollingOxidation kineticsThickness of oxide layerSEM
spellingShingle Siyuan Zhang
Mujun Long
Haohao Zhang
Songyuan Ai
Dengfu Chen
Peng Liu
Huamei Duan
Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
Journal of Materials Research and Technology
Continuous casting
Hot rolling
Oxidation kinetics
Thickness of oxide layer
SEM
title Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
title_full Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
title_fullStr Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
title_full_unstemmed Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
title_short Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface
title_sort experimental study on evolution of oxidation behavior on high temperature continuous casting slab surface
topic Continuous casting
Hot rolling
Oxidation kinetics
Thickness of oxide layer
SEM
url http://www.sciencedirect.com/science/article/pii/S2238785421001319
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AT dengfuchen experimentalstudyonevolutionofoxidationbehavioronhightemperaturecontinuouscastingslabsurface
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