Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes

To reduce CO2 emissions and turn a variety of industrial/agricultural wastes into valuable cementitious products, alkali-activated materials (AAM) are recognized as suitable substitutes for regular Portland cement (OPC). However, the concentrated aqueous alkali solutions used in conventional two-par...

Full description

Bibliographic Details
Main Authors: Reddy Bijivemula Kiran Kumar, Narasimhan Mattur C.
Format: Article
Language:English
Published: EDP Sciences 2023-01-01
Series:E3S Web of Conferences
Subjects:
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/42/e3sconf_icstce2023_03024.pdf
_version_ 1797756213473050624
author Reddy Bijivemula Kiran Kumar
Narasimhan Mattur C.
author_facet Reddy Bijivemula Kiran Kumar
Narasimhan Mattur C.
author_sort Reddy Bijivemula Kiran Kumar
collection DOAJ
description To reduce CO2 emissions and turn a variety of industrial/agricultural wastes into valuable cementitious products, alkali-activated materials (AAM) are recognized as suitable substitutes for regular Portland cement (OPC). However, the concentrated aqueous alkali solutions used in conventional two-part alkali activated materials are highly corrosive, viscous, and are difficult to handle in direct field applications. As a result, the potential for developing so-called "just add water" type one-part AAMs, as compared to traditional two-part AAM, is being explored, particularly in cast-in-situ applications. In the present study on corrosion of reinforcing steel bars in fly ash-slag (FA-GGBS) based one-part AAC mixtures, three parameters—the total binder content, the relative proportions of GGBS and Fly-ash and the percentage of sodium oxide (Na2O) - are recognized as the key factors in determining the strength and durability performance (including corrosion of rebars embedded in it) of a given AAC mix. Accordingly, experiments were conducted on AAC mixes with three binder contents (440, 460, and 480 kg/m3), three Slag/FA ratios (80/20, 70/30 and 60/40, by volume) and three alternate Na2O percentages (5, 6, and 7%, by weight of total binder content). Prismatic cylindrical test specimens of reinforced geopolymer concrete were prepared and half-cell potential and corrosion rate measurements were made after 28-, 56-, and 90 days of continuous exposure to 3% of NaCl solution, to accelerate the corrosion process. Measured corrosion current density and corrosion rates using a Electro-chemical Corrosion Analyser have indicated that the AAC mixture having a total binder content 440 kg/m3, GGBS/FS ratio of 70/30 and 6% Na2O content, exhibits best corrosion resistance amongst the various mixes tested herein, as measured up to the end of 90-days.
first_indexed 2024-03-12T17:58:13Z
format Article
id doaj.art-31215144cda640de88864252abde8885
institution Directory Open Access Journal
issn 2267-1242
language English
last_indexed 2024-03-12T17:58:13Z
publishDate 2023-01-01
publisher EDP Sciences
record_format Article
series E3S Web of Conferences
spelling doaj.art-31215144cda640de88864252abde88852023-08-02T13:18:12ZengEDP SciencesE3S Web of Conferences2267-12422023-01-014050302410.1051/e3sconf/202340503024e3sconf_icstce2023_03024Corrosion of steel rebars embedded in One-part Alkali activated concrete mixesReddy Bijivemula Kiran Kumar0Narasimhan Mattur C.1Department of Civil Engineering, NITKDepartment of Civil Engineering, NITKTo reduce CO2 emissions and turn a variety of industrial/agricultural wastes into valuable cementitious products, alkali-activated materials (AAM) are recognized as suitable substitutes for regular Portland cement (OPC). However, the concentrated aqueous alkali solutions used in conventional two-part alkali activated materials are highly corrosive, viscous, and are difficult to handle in direct field applications. As a result, the potential for developing so-called "just add water" type one-part AAMs, as compared to traditional two-part AAM, is being explored, particularly in cast-in-situ applications. In the present study on corrosion of reinforcing steel bars in fly ash-slag (FA-GGBS) based one-part AAC mixtures, three parameters—the total binder content, the relative proportions of GGBS and Fly-ash and the percentage of sodium oxide (Na2O) - are recognized as the key factors in determining the strength and durability performance (including corrosion of rebars embedded in it) of a given AAC mix. Accordingly, experiments were conducted on AAC mixes with three binder contents (440, 460, and 480 kg/m3), three Slag/FA ratios (80/20, 70/30 and 60/40, by volume) and three alternate Na2O percentages (5, 6, and 7%, by weight of total binder content). Prismatic cylindrical test specimens of reinforced geopolymer concrete were prepared and half-cell potential and corrosion rate measurements were made after 28-, 56-, and 90 days of continuous exposure to 3% of NaCl solution, to accelerate the corrosion process. Measured corrosion current density and corrosion rates using a Electro-chemical Corrosion Analyser have indicated that the AAC mixture having a total binder content 440 kg/m3, GGBS/FS ratio of 70/30 and 6% Na2O content, exhibits best corrosion resistance amongst the various mixes tested herein, as measured up to the end of 90-days.https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/42/e3sconf_icstce2023_03024.pdfalkali activated materialsrebar corrosioncarbon emissionselectrochemical methodsgeopolymer concretes
spellingShingle Reddy Bijivemula Kiran Kumar
Narasimhan Mattur C.
Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
E3S Web of Conferences
alkali activated materials
rebar corrosion
carbon emissions
electrochemical methods
geopolymer concretes
title Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
title_full Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
title_fullStr Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
title_full_unstemmed Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
title_short Corrosion of steel rebars embedded in One-part Alkali activated concrete mixes
title_sort corrosion of steel rebars embedded in one part alkali activated concrete mixes
topic alkali activated materials
rebar corrosion
carbon emissions
electrochemical methods
geopolymer concretes
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/42/e3sconf_icstce2023_03024.pdf
work_keys_str_mv AT reddybijivemulakirankumar corrosionofsteelrebarsembeddedinonepartalkaliactivatedconcretemixes
AT narasimhanmatturc corrosionofsteelrebarsembeddedinonepartalkaliactivatedconcretemixes