Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies

Abstract European Bronze and Iron Age vitrified hillforts have been known since the 1700s, but archaeological interpretations regarding their function and use are still debated. We carried out a series of experiments to constrain conditions that led to the vitrification of the inner wall rocks in th...

Full description

Bibliographic Details
Main Authors: John S. McCloy, José Marcial, Jack S. Clarke, Mostafa Ahmadzadeh, John A. Wolff, Edward P. Vicenzi, David L. Bollinger, Erik Ogenhall, Mia Englund, Carolyn I. Pearce, Rolf Sjöblom, Albert A. Kruger
Format: Article
Language:English
Published: Nature Portfolio 2021-01-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-020-80485-w
_version_ 1818858720756498432
author John S. McCloy
José Marcial
Jack S. Clarke
Mostafa Ahmadzadeh
John A. Wolff
Edward P. Vicenzi
David L. Bollinger
Erik Ogenhall
Mia Englund
Carolyn I. Pearce
Rolf Sjöblom
Albert A. Kruger
author_facet John S. McCloy
José Marcial
Jack S. Clarke
Mostafa Ahmadzadeh
John A. Wolff
Edward P. Vicenzi
David L. Bollinger
Erik Ogenhall
Mia Englund
Carolyn I. Pearce
Rolf Sjöblom
Albert A. Kruger
author_sort John S. McCloy
collection DOAJ
description Abstract European Bronze and Iron Age vitrified hillforts have been known since the 1700s, but archaeological interpretations regarding their function and use are still debated. We carried out a series of experiments to constrain conditions that led to the vitrification of the inner wall rocks in the hillfort at Broborg, Sweden. Potential source rocks were collected locally and heat treated in the laboratory, varying maximum temperature, cooling rate, and starting particle size. Crystalline and amorphous phases were quantified using X-ray diffraction both in situ, during heating and cooling, and ex situ, after heating and quenching. Textures, phases, and glass compositions obtained were compared with those for rock samples from the vitrified part of the wall, as well as with equilibrium crystallization calculations. ‘Dark glass’ and its associated minerals formed from amphibolite or dolerite rocks melted at 1000–1200 °C under reducing atmosphere then slow cooled. ‘Clear glass’ formed from non-equilibrium partial melting of feldspar in granitoid rocks. This study aids archaeological forensic investigation of vitrified hillforts and interpretation of source rock material by mapping mineralogical changes and glass production under various heating conditions.
first_indexed 2024-12-19T09:00:47Z
format Article
id doaj.art-31320ea7091548e0a36e406b6bc90cbd
institution Directory Open Access Journal
issn 2045-2322
language English
last_indexed 2024-12-19T09:00:47Z
publishDate 2021-01-01
publisher Nature Portfolio
record_format Article
series Scientific Reports
spelling doaj.art-31320ea7091548e0a36e406b6bc90cbd2022-12-21T20:28:29ZengNature PortfolioScientific Reports2045-23222021-01-0111111810.1038/s41598-020-80485-wReproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologiesJohn S. McCloy0José Marcial1Jack S. Clarke2Mostafa Ahmadzadeh3John A. Wolff4Edward P. Vicenzi5David L. Bollinger6Erik Ogenhall7Mia Englund8Carolyn I. Pearce9Rolf Sjöblom10Albert A. Kruger11School of Mechanical and Materials Engineering, Washington State UniversitySchool of Mechanical and Materials Engineering, Washington State UniversityDepartment of Materials Science and Engineering, University of SheffieldSchool of Mechanical and Materials Engineering, Washington State UniversitySchool of the Environment, Washington State UniversityMuseum Conservation Institute, Smithsonian InstitutionMaterials Science and Engineering Program, Washington State UniversityThe Archaeologists, National Historical Museums (SHM)The Archaeologists, National Historical Museums (SHM)Pacific Northwest National LaboratoryLuleå University of TechnologyUS Department of EnergyAbstract European Bronze and Iron Age vitrified hillforts have been known since the 1700s, but archaeological interpretations regarding their function and use are still debated. We carried out a series of experiments to constrain conditions that led to the vitrification of the inner wall rocks in the hillfort at Broborg, Sweden. Potential source rocks were collected locally and heat treated in the laboratory, varying maximum temperature, cooling rate, and starting particle size. Crystalline and amorphous phases were quantified using X-ray diffraction both in situ, during heating and cooling, and ex situ, after heating and quenching. Textures, phases, and glass compositions obtained were compared with those for rock samples from the vitrified part of the wall, as well as with equilibrium crystallization calculations. ‘Dark glass’ and its associated minerals formed from amphibolite or dolerite rocks melted at 1000–1200 °C under reducing atmosphere then slow cooled. ‘Clear glass’ formed from non-equilibrium partial melting of feldspar in granitoid rocks. This study aids archaeological forensic investigation of vitrified hillforts and interpretation of source rock material by mapping mineralogical changes and glass production under various heating conditions.https://doi.org/10.1038/s41598-020-80485-w
spellingShingle John S. McCloy
José Marcial
Jack S. Clarke
Mostafa Ahmadzadeh
John A. Wolff
Edward P. Vicenzi
David L. Bollinger
Erik Ogenhall
Mia Englund
Carolyn I. Pearce
Rolf Sjöblom
Albert A. Kruger
Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
Scientific Reports
title Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
title_full Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
title_fullStr Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
title_full_unstemmed Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
title_short Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies
title_sort reproduction of melting behavior for vitrified hillforts based on amphibolite granite and basalt lithologies
url https://doi.org/10.1038/s41598-020-80485-w
work_keys_str_mv AT johnsmccloy reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT josemarcial reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT jacksclarke reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT mostafaahmadzadeh reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT johnawolff reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT edwardpvicenzi reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT davidlbollinger reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT erikogenhall reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT miaenglund reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT carolynipearce reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT rolfsjoblom reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies
AT albertakruger reproductionofmeltingbehaviorforvitrifiedhillfortsbasedonamphibolitegraniteandbasaltlithologies