Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes
1,2,3-Trimethylbenzimidazolium iodide and its analogue salts with one or two substituents on benzene ring (X = NO2, Br,Cl, CH3) are, due to the reactivity of the 2-methyl group, able to react with para-substituted aromatic aldehydes (X = OH, OCH3, CH3, NMe2, NO2) using piperidine as a catalyst. 1-Me...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2005-12-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/vol70/No12/JSCS_V70_No12-01.pdf |
| _version_ | 1818961628227436544 |
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| author | CORINA CERNATESCU EUGENIA COMANITA |
| author_facet | CORINA CERNATESCU EUGENIA COMANITA |
| author_sort | CORINA CERNATESCU |
| collection | DOAJ |
| description | 1,2,3-Trimethylbenzimidazolium iodide and its analogue salts with one or two substituents on benzene ring (X = NO2, Br,Cl, CH3) are, due to the reactivity of the 2-methyl group, able to react with para-substituted aromatic aldehydes (X = OH, OCH3, CH3, NMe2, NO2) using piperidine as a catalyst. 1-Methyl-2-styrylbenzimidazole iodomethylates were obtained and their structure elucidated by means of NMR and IR spectroscopy. The compounds are interesting as hemicyanine dyes. They lend themselves to studies based on electronic absorption spectroscopy and they have potential practical applications linked to their photosensitive properties. |
| first_indexed | 2024-12-20T12:16:27Z |
| format | Article |
| id | doaj.art-314a4c005e144d88b0531ca682ccf9bb |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-20T12:16:27Z |
| publishDate | 2005-12-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-314a4c005e144d88b0531ca682ccf9bb2022-12-21T19:41:06ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392005-12-01701213811388Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydesCORINA CERNATESCUEUGENIA COMANITA1,2,3-Trimethylbenzimidazolium iodide and its analogue salts with one or two substituents on benzene ring (X = NO2, Br,Cl, CH3) are, due to the reactivity of the 2-methyl group, able to react with para-substituted aromatic aldehydes (X = OH, OCH3, CH3, NMe2, NO2) using piperidine as a catalyst. 1-Methyl-2-styrylbenzimidazole iodomethylates were obtained and their structure elucidated by means of NMR and IR spectroscopy. The compounds are interesting as hemicyanine dyes. They lend themselves to studies based on electronic absorption spectroscopy and they have potential practical applications linked to their photosensitive properties.http://www.shd.org.yu/HtDocs/SHD/vol70/No12/JSCS_V70_No12-01.pdfbenzimidazolium iodidescondensation reactions2-stryrylbenzimidazole iodomethylates |
| spellingShingle | CORINA CERNATESCU EUGENIA COMANITA Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes Journal of the Serbian Chemical Society benzimidazolium iodides condensation reactions 2-stryrylbenzimidazole iodomethylates |
| title | Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes |
| title_full | Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes |
| title_fullStr | Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes |
| title_full_unstemmed | Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes |
| title_short | Benzazole derivatives. IV. Reaction of 1,2,3-trimethylbenzimidazolium salts with aromatic aldehydes |
| title_sort | benzazole derivatives iv reaction of 1 2 3 trimethylbenzimidazolium salts with aromatic aldehydes |
| topic | benzimidazolium iodides condensation reactions 2-stryrylbenzimidazole iodomethylates |
| url | http://www.shd.org.yu/HtDocs/SHD/vol70/No12/JSCS_V70_No12-01.pdf |
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