Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules

For the last two decades, the development of substrates for Surface Enhanced Raman Spectroscopy (SERS) has been continuously pushed for better performances. In this research, we designed SERS substrates with better detection capability and more efficient sample collection. In particular, morphology-...

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Main Authors: Hoang Duy Minh, Nguyen Duc Thang, Nguyen Thao Linh Chi, Luong Duc Anh, Le Ngoc Long, Tran Van Khai, Huynh Cong Khanh, Nguyen Dang Khoa, Tran Hoang Minh
Format: Article
Language:English
Published: IOP Publishing 2024-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ad194a
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author Hoang Duy Minh
Nguyen Duc Thang
Nguyen Thao Linh Chi
Luong Duc Anh
Le Ngoc Long
Tran Van Khai
Huynh Cong Khanh
Nguyen Dang Khoa
Tran Hoang Minh
author_facet Hoang Duy Minh
Nguyen Duc Thang
Nguyen Thao Linh Chi
Luong Duc Anh
Le Ngoc Long
Tran Van Khai
Huynh Cong Khanh
Nguyen Dang Khoa
Tran Hoang Minh
author_sort Hoang Duy Minh
collection DOAJ
description For the last two decades, the development of substrates for Surface Enhanced Raman Spectroscopy (SERS) has been continuously pushed for better performances. In this research, we designed SERS substrates with better detection capability and more efficient sample collection. In particular, morphology-controlled Ag nanoparticles were deposited onto cotton swab (cotton Q-tip), followed by a thin cover layer of graphene oxide by the dip-coating method. The graphene oxide overlay was expected to not only protect Ag nanoparticles from degradation by the environment but also contribute to sample adsorption and signal enhancement. To demonstrate the performance of the SERS substrates, different concentrations of Rhodamine B as low as 10 ^–10 M were successfully detected and the enhancement factors were estimated to be 3 × 10 ^10 –5 × 10 ^10 . It is our expectation that these cotton swab-based substrates will contribute to our ongoing efforts toward low-cost, high-efficiency and durable SERS substrate.
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spelling doaj.art-315b0f8d65b44c4daf7212ac926805972024-02-07T11:43:57ZengIOP PublishingMaterials Research Express2053-15912024-01-0111202500210.1088/2053-1591/ad194aHybrid SERS substrate based on cotton swab for sensitive detection of organic moleculesHoang Duy Minh0Nguyen Duc Thang1Nguyen Thao Linh Chi2Luong Duc Anh3Le Ngoc Long4Tran Van Khai5https://orcid.org/0000-0001-7629-6598Huynh Cong Khanh6Nguyen Dang Khoa7Tran Hoang Minh8https://orcid.org/0000-0002-1988-4286Faculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology - Vietnam National University (HCMUT-VNU) , 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, VietnamFor the last two decades, the development of substrates for Surface Enhanced Raman Spectroscopy (SERS) has been continuously pushed for better performances. In this research, we designed SERS substrates with better detection capability and more efficient sample collection. In particular, morphology-controlled Ag nanoparticles were deposited onto cotton swab (cotton Q-tip), followed by a thin cover layer of graphene oxide by the dip-coating method. The graphene oxide overlay was expected to not only protect Ag nanoparticles from degradation by the environment but also contribute to sample adsorption and signal enhancement. To demonstrate the performance of the SERS substrates, different concentrations of Rhodamine B as low as 10 ^–10 M were successfully detected and the enhancement factors were estimated to be 3 × 10 ^10 –5 × 10 ^10 . It is our expectation that these cotton swab-based substrates will contribute to our ongoing efforts toward low-cost, high-efficiency and durable SERS substrate.https://doi.org/10.1088/2053-1591/ad194aSERShybrid nanomaterialplasmonic materialsilver nanoparticlesflexible substrategraphene oxide
spellingShingle Hoang Duy Minh
Nguyen Duc Thang
Nguyen Thao Linh Chi
Luong Duc Anh
Le Ngoc Long
Tran Van Khai
Huynh Cong Khanh
Nguyen Dang Khoa
Tran Hoang Minh
Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
Materials Research Express
SERS
hybrid nanomaterial
plasmonic material
silver nanoparticles
flexible substrate
graphene oxide
title Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
title_full Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
title_fullStr Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
title_full_unstemmed Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
title_short Hybrid SERS substrate based on cotton swab for sensitive detection of organic molecules
title_sort hybrid sers substrate based on cotton swab for sensitive detection of organic molecules
topic SERS
hybrid nanomaterial
plasmonic material
silver nanoparticles
flexible substrate
graphene oxide
url https://doi.org/10.1088/2053-1591/ad194a
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