Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane
A rational synthetic approach is introduced to enable hydrogen insertion into oxides by forming a solid solution of a reducible oxide with a less reducible oxide as exemplified with RuO<sub>2</sub> and TiO<sub>2</sub> (Ru_x, a mixture of x% RuO<sub>2</sub> with (1...
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MDPI AG
2023-08-01
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| Series: | Inorganics |
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| Online Access: | https://www.mdpi.com/2304-6740/11/8/330 |
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| author | Wei Wang Yu Wang Phillip Timmer Alexander Spriewald-Luciano Tim Weber Lorena Glatthaar Yun Guo Bernd M. Smarsly Herbert Over |
| author_facet | Wei Wang Yu Wang Phillip Timmer Alexander Spriewald-Luciano Tim Weber Lorena Glatthaar Yun Guo Bernd M. Smarsly Herbert Over |
| author_sort | Wei Wang |
| collection | DOAJ |
| description | A rational synthetic approach is introduced to enable hydrogen insertion into oxides by forming a solid solution of a reducible oxide with a less reducible oxide as exemplified with RuO<sub>2</sub> and TiO<sub>2</sub> (Ru_x, a mixture of x% RuO<sub>2</sub> with (100−x)% TiO<sub>2</sub>). Hydrogen exposure at 250 °C to Ru_x (Ru_x_250R) results in substantial hydrogen incorporation accompanied by lattice strain that in turn induces pronounced activity variations. Here, we demonstrate that hydrogen incorporation in mixed oxides promotes the oxidation catalysis of propane combustion with Ru_60_250R being the catalytically most active catalyst. |
| first_indexed | 2024-03-10T23:51:13Z |
| format | Article |
| id | doaj.art-3175d77041bd47ec91ed694f07ba1eec |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-10T23:51:13Z |
| publishDate | 2023-08-01 |
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| series | Inorganics |
| spelling | doaj.art-3175d77041bd47ec91ed694f07ba1eec2023-11-19T01:35:41ZengMDPI AGInorganics2304-67402023-08-0111833010.3390/inorganics11080330Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of PropaneWei Wang0Yu Wang1Phillip Timmer2Alexander Spriewald-Luciano3Tim Weber4Lorena Glatthaar5Yun Guo6Bernd M. Smarsly7Herbert Over8Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, ChinaKey Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, ChinaInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyKey Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, ChinaInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyInstitute of Physical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, GermanyA rational synthetic approach is introduced to enable hydrogen insertion into oxides by forming a solid solution of a reducible oxide with a less reducible oxide as exemplified with RuO<sub>2</sub> and TiO<sub>2</sub> (Ru_x, a mixture of x% RuO<sub>2</sub> with (100−x)% TiO<sub>2</sub>). Hydrogen exposure at 250 °C to Ru_x (Ru_x_250R) results in substantial hydrogen incorporation accompanied by lattice strain that in turn induces pronounced activity variations. Here, we demonstrate that hydrogen incorporation in mixed oxides promotes the oxidation catalysis of propane combustion with Ru_60_250R being the catalytically most active catalyst.https://www.mdpi.com/2304-6740/11/8/330catalyst promotormixed oxideshydrogenated Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub>propane combustionhydrogen-induced variation in the activity |
| spellingShingle | Wei Wang Yu Wang Phillip Timmer Alexander Spriewald-Luciano Tim Weber Lorena Glatthaar Yun Guo Bernd M. Smarsly Herbert Over Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane Inorganics catalyst promotor mixed oxides hydrogenated Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> propane combustion hydrogen-induced variation in the activity |
| title | Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane |
| title_full | Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane |
| title_fullStr | Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane |
| title_full_unstemmed | Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane |
| title_short | Hydrogen Incorporation in Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> Mixed Oxides Promotes Total Oxidation of Propane |
| title_sort | hydrogen incorporation in ru sub x sub ti sub 1 x sub o sub 2 sub mixed oxides promotes total oxidation of propane |
| topic | catalyst promotor mixed oxides hydrogenated Ru<sub>x</sub>Ti<sub>1−x</sub>O<sub>2</sub> propane combustion hydrogen-induced variation in the activity |
| url | https://www.mdpi.com/2304-6740/11/8/330 |
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