Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate
In the title structure, [Ti2(C16H16N2O2)2O2]·2CHCl3, the Ti atom is coordinated in a distorted octahedral geometry by the O,N,N′,O′ donor set of the salalen ligand and by two μ2-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813029656 |
| _version_ | 1818322604904153088 |
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| author | Andrei V. Churakov Irina V. Vasilenko Yulia A. Piskun Sergey S. Karlov Kirill V. Zaitsev |
| author_facet | Andrei V. Churakov Irina V. Vasilenko Yulia A. Piskun Sergey S. Karlov Kirill V. Zaitsev |
| author_sort | Andrei V. Churakov |
| collection | DOAJ |
| description | In the title structure, [Ti2(C16H16N2O2)2O2]·2CHCl3, the Ti atom is coordinated in a distorted octahedral geometry by the O,N,N′,O′ donor set of the salalen ligand and by two μ2-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti2(μ2-O)2 fragment, the metal–oxygen distances are significantly different [1.7962 (19) and 1.9292 (19) Å]. In the crystal, the chloroform molecule is anchored via an N—H...Cl and a bifurcated C—H...(O,O) hydrogen bond. Slipped π–π stacking [shortest C...C distance = 3.585 (4) Å] and C—H...π interactions contribute to the coherence of the structure. |
| first_indexed | 2024-12-13T10:59:27Z |
| format | Article |
| id | doaj.art-317edc5022154858a6f4a768930eb86a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:59:27Z |
| publishDate | 2013-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-317edc5022154858a6f4a768930eb86a2022-12-21T23:49:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m635m63610.1107/S1600536813029656Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvateAndrei V. ChurakovIrina V. VasilenkoYulia A. PiskunSergey S. KarlovKirill V. ZaitsevIn the title structure, [Ti2(C16H16N2O2)2O2]·2CHCl3, the Ti atom is coordinated in a distorted octahedral geometry by the O,N,N′,O′ donor set of the salalen ligand and by two μ2-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti2(μ2-O)2 fragment, the metal–oxygen distances are significantly different [1.7962 (19) and 1.9292 (19) Å]. In the crystal, the chloroform molecule is anchored via an N—H...Cl and a bifurcated C—H...(O,O) hydrogen bond. Slipped π–π stacking [shortest C...C distance = 3.585 (4) Å] and C—H...π interactions contribute to the coherence of the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813029656 |
| spellingShingle | Andrei V. Churakov Irina V. Vasilenko Yulia A. Piskun Sergey S. Karlov Kirill V. Zaitsev Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate Acta Crystallographica Section E |
| title | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_full | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_fullStr | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_full_unstemmed | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_short | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_sort | di 956 oxido bis 2 2 8242 ethane 1 2 diylbis nitrilomethanylylidene diphenolato titanium iv chloroform disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813029656 |
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