4-Amino-13-(1-naphthyl)-[2,2]paracyclophane
The title compound [systematic name: 12-amino-42-(1-naphthyl)-1,4(1,4)-dibenzenacyclohexaphane], C26H23N, was synthesized from 4-amino-13-bromo-[2,2]paracyclophane and 1-naphthaleneboronic acid in the presence of 1,4-dioxane. It is a new cyclophane-derived compound which can be regarded as a prospec...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808005333 |
| _version_ | 1819002678953377792 |
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| author | Yudao Ma Jikun Li Rentao Wu Yanmin Huo Junshan Sun |
| author_facet | Yudao Ma Jikun Li Rentao Wu Yanmin Huo Junshan Sun |
| author_sort | Yudao Ma |
| collection | DOAJ |
| description | The title compound [systematic name: 12-amino-42-(1-naphthyl)-1,4(1,4)-dibenzenacyclohexaphane], C26H23N, was synthesized from 4-amino-13-bromo-[2,2]paracyclophane and 1-naphthaleneboronic acid in the presence of 1,4-dioxane. It is a new cyclophane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclophane units are very slightly deformed from planarity as shallow boats. |
| first_indexed | 2024-12-20T23:08:56Z |
| format | Article |
| id | doaj.art-31a4cd27dd854528a475b764f60b2dc8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:08:56Z |
| publishDate | 2008-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-31a4cd27dd854528a475b764f60b2dc82022-12-21T19:23:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644o650o65010.1107/S16005368080053334-Amino-13-(1-naphthyl)-[2,2]paracyclophaneYudao MaJikun LiRentao WuYanmin HuoJunshan SunThe title compound [systematic name: 12-amino-42-(1-naphthyl)-1,4(1,4)-dibenzenacyclohexaphane], C26H23N, was synthesized from 4-amino-13-bromo-[2,2]paracyclophane and 1-naphthaleneboronic acid in the presence of 1,4-dioxane. It is a new cyclophane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclophane units are very slightly deformed from planarity as shallow boats.http://scripts.iucr.org/cgi-bin/paper?S1600536808005333 |
| spellingShingle | Yudao Ma Jikun Li Rentao Wu Yanmin Huo Junshan Sun 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane Acta Crystallographica Section E |
| title | 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane |
| title_full | 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane |
| title_fullStr | 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane |
| title_full_unstemmed | 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane |
| title_short | 4-Amino-13-(1-naphthyl)-[2,2]paracyclophane |
| title_sort | 4 amino 13 1 naphthyl 2 2 paracyclophane |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808005333 |
| work_keys_str_mv | AT yudaoma 4amino131naphthyl22paracyclophane AT jikunli 4amino131naphthyl22paracyclophane AT rentaowu 4amino131naphthyl22paracyclophane AT yanminhuo 4amino131naphthyl22paracyclophane AT junshansun 4amino131naphthyl22paracyclophane |