Oxidation of Iodine to Dihaloiodate(I) Salts of Amines With Hydrogen Peroxides and Their Crystal Structures

Oxidation of Iodine to Dihaloiodate(I) Salts of Amines With Hydrogen Peroxides and Their Crystal Structures

Herein we report a general preparation of dihaloiodate salts of heterocyclic amines (tertiary and quaternary) with sterically accessible and hindered nitrogen atom. A number of such compounds were prepared from preformed HICl2 or HIBr2 formed in situ by the reaction of corresponding hydrogen halide,...

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Bibliographic Details
Main Authors: Griša Grigorij Prinčič, Nik Maselj, Evgeny Goreshnik, Jernej Iskra
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-05-01
Series:Frontiers in Chemistry
Subjects:
Hypervalent iodine compounds
dihaloiodates
halogenation
hydrogen peroxide
crystal structure
amine base
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2022.912383/full

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