The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites

This research focuses on recycling rubber tire waste through pyrolysis to produce recovered carbon black (rCB). The rCB is combined with recycled low-density polyethylene (rLDPE), calcium carbonate (CaCO3), fatty acid, metallic stearate, and polyethylene (PE) wax to create an rCB masterbatch for hou...

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Main Authors: Leow Voon Jou, Teh Pei Leng, Yeoh Cheow Keat, Abdul Rahim Nor Azura, Wong Wee Chun, Voon Chun Hong, Mohamed Rasidi Mohamad Syahmie, Lim Bee Ying
Format: Article
Language:English
Published: De Gruyter 2023-07-01
Series:e-Polymers
Subjects:
Online Access:https://doi.org/10.1515/epoly-2023-0025
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author Leow Voon Jou
Teh Pei Leng
Yeoh Cheow Keat
Abdul Rahim Nor Azura
Wong Wee Chun
Voon Chun Hong
Mohamed Rasidi Mohamad Syahmie
Lim Bee Ying
author_facet Leow Voon Jou
Teh Pei Leng
Yeoh Cheow Keat
Abdul Rahim Nor Azura
Wong Wee Chun
Voon Chun Hong
Mohamed Rasidi Mohamad Syahmie
Lim Bee Ying
author_sort Leow Voon Jou
collection DOAJ
description This research focuses on recycling rubber tire waste through pyrolysis to produce recovered carbon black (rCB). The rCB is combined with recycled low-density polyethylene (rLDPE), calcium carbonate (CaCO3), fatty acid, metallic stearate, and polyethylene (PE) wax to create an rCB masterbatch for household packaging. Surface modification of CaCO3 particles using stearic acid improves the compatibility with LDPE. The study investigates mechanical properties, morphology, melt flow index (MFI), X-ray diffraction, and thermogravimetric analysis in three systems: uncoated, coated, and a hybrid combination of coated and uncoated CaCO3 in LDPE/rCB masterbatch composites. The coated system demonstrates higher mechanical properties and improved compatibility between CaCO3 and LDPE. All three systems exhibit enhanced thermal stability and MFI compared to virgin LDPE, with the coated system showing the most significant improvement. The study showcases the potential of LDPE/rCB masterbatch composites for household packaging, with the coated system displaying the optimum performance across various characteristics.
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spelling doaj.art-31bfcca4642d4adb8e0be554712b01022023-07-10T06:03:30ZengDe Gruytere-Polymers1618-72292023-07-0123111556710.1515/epoly-2023-0025The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene compositesLeow Voon Jou0Teh Pei Leng1Yeoh Cheow Keat2Abdul Rahim Nor Azura3Wong Wee Chun4Voon Chun Hong5Mohamed Rasidi Mohamad Syahmie6Lim Bee Ying7Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaFaculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaFaculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaFaculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaEcopower Synergy Sdn. Bhd., 1A, Jalan Kenari 9, Bandar Puchong Jaya, 47100Puchong, Selangor, MalaysiaInstitute of Nano Electronic Engineering, Universiti Malaysia Perlis, Lot 106, 108 & 110, Blok A, Taman Pertiwi Indah, Jalan Kangar-Alor Setar, Seriab, 01000Kangar, Perlis, MalaysiaFaculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaFaculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, Universiti Malaysia Perlis, Taman Muhibbah, 02600Arau, Perlis, MalaysiaThis research focuses on recycling rubber tire waste through pyrolysis to produce recovered carbon black (rCB). The rCB is combined with recycled low-density polyethylene (rLDPE), calcium carbonate (CaCO3), fatty acid, metallic stearate, and polyethylene (PE) wax to create an rCB masterbatch for household packaging. Surface modification of CaCO3 particles using stearic acid improves the compatibility with LDPE. The study investigates mechanical properties, morphology, melt flow index (MFI), X-ray diffraction, and thermogravimetric analysis in three systems: uncoated, coated, and a hybrid combination of coated and uncoated CaCO3 in LDPE/rCB masterbatch composites. The coated system demonstrates higher mechanical properties and improved compatibility between CaCO3 and LDPE. All three systems exhibit enhanced thermal stability and MFI compared to virgin LDPE, with the coated system showing the most significant improvement. The study showcases the potential of LDPE/rCB masterbatch composites for household packaging, with the coated system displaying the optimum performance across various characteristics.https://doi.org/10.1515/epoly-2023-0025recovered carbon blacklow-density polyethylenercb masterbatchstearic acid-coated calcium carbonate
spellingShingle Leow Voon Jou
Teh Pei Leng
Yeoh Cheow Keat
Abdul Rahim Nor Azura
Wong Wee Chun
Voon Chun Hong
Mohamed Rasidi Mohamad Syahmie
Lim Bee Ying
The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
e-Polymers
recovered carbon black
low-density polyethylene
rcb masterbatch
stearic acid-coated calcium carbonate
title The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
title_full The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
title_fullStr The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
title_full_unstemmed The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
title_short The effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low-density polyethylene composites
title_sort effect of coated calcium carbonate using stearic acid on the recovered carbon black masterbatch in low density polyethylene composites
topic recovered carbon black
low-density polyethylene
rcb masterbatch
stearic acid-coated calcium carbonate
url https://doi.org/10.1515/epoly-2023-0025
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