[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV)
In the title four-coordinate complex, [Ti(C2H6N)2(C31H28O4)], two symmetry-independent molecules are present in the asymmetric unit. The TiIV atom displays a distorted tetrahedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3)&#...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002929 |
| _version_ | 1818958074207010816 |
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| author | Leslie Roteta Joseph M. Tanski |
| author_facet | Leslie Roteta Joseph M. Tanski |
| author_sort | Leslie Roteta |
| collection | DOAJ |
| description | In the title four-coordinate complex, [Ti(C2H6N)2(C31H28O4)], two symmetry-independent molecules are present in the asymmetric unit. The TiIV atom displays a distorted tetrahedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the TiIV atom and the dimethylamide ligands. |
| first_indexed | 2024-12-20T11:19:57Z |
| format | Article |
| id | doaj.art-31c20e167bcb41ef8884fe027d9b9b27 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:19:57Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-31c20e167bcb41ef8884fe027d9b9b272022-12-21T19:42:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m217m21710.1107/S1600536812002929[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV)Leslie RotetaJoseph M. TanskiIn the title four-coordinate complex, [Ti(C2H6N)2(C31H28O4)], two symmetry-independent molecules are present in the asymmetric unit. The TiIV atom displays a distorted tetrahedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the TiIV atom and the dimethylamide ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536812002929 |
| spellingShingle | Leslie Roteta Joseph M. Tanski [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) Acta Crystallographica Section E |
| title | [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) |
| title_full | [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) |
| title_fullStr | [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) |
| title_full_unstemmed | [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) |
| title_short | [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O:O′]bis(N-methylmethanaminato)titanium(IV) |
| title_sort | 4r 5r 2 2 dimethyl 1 3 dioxolane 4 5 diyl bis diphenylmethanolato amp 954 2o o amp 8242 bis n methylmethanaminato titanium iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002929 |
| work_keys_str_mv | AT leslieroteta 4r5r22dimethyl13dioxolane45diylbisdiphenylmethanolatoamp9542ooamp8242bisnmethylmethanaminatotitaniumiv AT josephmtanski 4r5r22dimethyl13dioxolane45diylbisdiphenylmethanolatoamp9542ooamp8242bisnmethylmethanaminatotitaniumiv |