2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid
The self-assembly of [Zn(L)(H2O)2]·Cl2 and 1,2-cyclopentanedicarboxylic acid generates a 2D hydrogen-bonded polymer [Zn(L)(Hcpdc)] (L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.1807.12]docosane, H2 cpdc= 1,2-cyclopentanedicarboxylic acid) (1). Complex 1 is characterized by X-ray crystallograph...
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| Format: | Article |
| Language: | English |
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De Gruyter
2014-12-01
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| Series: | Main Group Metal Chemistry |
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| Online Access: | https://doi.org/10.1515/mgmc-2014-0016 |
| _version_ | 1818716828885581824 |
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| author | Choi Ki-Young |
| author_facet | Choi Ki-Young |
| author_sort | Choi Ki-Young |
| collection | DOAJ |
| description | The self-assembly of [Zn(L)(H2O)2]·Cl2 and 1,2-cyclopentanedicarboxylic acid generates a 2D hydrogen-bonded polymer [Zn(L)(Hcpdc)] (L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.1807.12]docosane, H2 cpdc= 1,2-cyclopentanedicarboxylic acid) (1). Complex 1 is characterized by X-ray crystallography, spectroscopy, and thermogravimetric analyzer. The crystal structure of 1 shows a distorted octahedral coordination geometry around the zinc (II) ion, with the four secondary amines of the macrocycle and two carboxylate oxygen atoms of the Hcpdc- ligand in the trans position. The compound crystallizes in the monoclinic system P21/c with a=8.6002(10), b=10.4906(11), c=19.008(2) Å, β (°)=92.949(7)°, V=1712.6(3) Å3, Z=2. The IR spectrum and TGA behavior of the compound are significantly affected by the Hcpdc- ligand. |
| first_indexed | 2024-12-17T19:25:28Z |
| format | Article |
| id | doaj.art-31c4f49425ff4d62a738b5a31a2e7f84 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-17T19:25:28Z |
| publishDate | 2014-12-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-31c4f49425ff4d62a738b5a31a2e7f842022-12-21T21:35:24ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192014-12-01375-612512910.1515/mgmc-2014-00162D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acidChoi Ki-Young0Department of Chemistry Education, Kongju National University, Kongju 314-701, Republic of KoreaThe self-assembly of [Zn(L)(H2O)2]·Cl2 and 1,2-cyclopentanedicarboxylic acid generates a 2D hydrogen-bonded polymer [Zn(L)(Hcpdc)] (L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.1807.12]docosane, H2 cpdc= 1,2-cyclopentanedicarboxylic acid) (1). Complex 1 is characterized by X-ray crystallography, spectroscopy, and thermogravimetric analyzer. The crystal structure of 1 shows a distorted octahedral coordination geometry around the zinc (II) ion, with the four secondary amines of the macrocycle and two carboxylate oxygen atoms of the Hcpdc- ligand in the trans position. The compound crystallizes in the monoclinic system P21/c with a=8.6002(10), b=10.4906(11), c=19.008(2) Å, β (°)=92.949(7)°, V=1712.6(3) Å3, Z=2. The IR spectrum and TGA behavior of the compound are significantly affected by the Hcpdc- ligand.https://doi.org/10.1515/mgmc-2014-00161,2-cyclopentanedicarboxylic acid2d hydrogen-bonded polymercrystal structuretetraaza macrocyclezinc(ii) complex |
| spellingShingle | Choi Ki-Young 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid Main Group Metal Chemistry 1,2-cyclopentanedicarboxylic acid 2d hydrogen-bonded polymer crystal structure tetraaza macrocycle zinc(ii) complex |
| title | 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid |
| title_full | 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid |
| title_fullStr | 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid |
| title_full_unstemmed | 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid |
| title_short | 2D Hydrogen-bonded polymer assembled by zinc(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylic acid |
| title_sort | 2d hydrogen bonded polymer assembled by zinc ii tetraaza macrocyclic complex and 1 2 cyclopentanedicarboxylic acid |
| topic | 1,2-cyclopentanedicarboxylic acid 2d hydrogen-bonded polymer crystal structure tetraaza macrocycle zinc(ii) complex |
| url | https://doi.org/10.1515/mgmc-2014-0016 |
| work_keys_str_mv | AT choikiyoung 2dhydrogenbondedpolymerassembledbyzinciitetraazamacrocycliccomplexand12cyclopentanedicarboxylicacid |