Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass

Photonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the...

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Main Authors: Andrea Chiappini, Davide Faccialà, Nina I. Novikova, Samim Sardar, Cosimo D’Andrea, Guido Scavia, Chiara Botta, Tersilla Virgili
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/3/654
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author Andrea Chiappini
Davide Faccialà
Nina I. Novikova
Samim Sardar
Cosimo D’Andrea
Guido Scavia
Chiara Botta
Tersilla Virgili
author_facet Andrea Chiappini
Davide Faccialà
Nina I. Novikova
Samim Sardar
Cosimo D’Andrea
Guido Scavia
Chiara Botta
Tersilla Virgili
author_sort Andrea Chiappini
collection DOAJ
description Photonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the morphology (dimension) and optical properties (refractive index) of the building blocks. In this study, we report the fabrication and optical characterization of photonic glasses obtained via a self-assembling technique. Furthermore, we have demonstrated that the infiltration of these systems with a green-emitting polymer enhances the properties of the polymer, resulting in a large increase in its photoluminescence quantum yield and a 3 ps growing time of the photoluminescence time decay Finally, the development of the aforementioned system can serve as a suitable low-cost platform for the realization of lasers and fluorescence-based bio-sensors.
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spelling doaj.art-31cda92bab134358a68a531fdf33f7922024-02-09T15:18:59ZengMDPI AGMolecules1420-30492024-01-0129365410.3390/molecules29030654Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic GlassAndrea Chiappini0Davide Faccialà1Nina I. Novikova2Samim Sardar3Cosimo D’Andrea4Guido Scavia5Chiara Botta6Tersilla Virgili7Istituto di Fotonica e Nanotecnologia—CNR, IFN and FBK Photonics Unit, Via alla Cascata 56/c, Povo, 38123 Trento, ItalyIstituto di Fotonica e Nanotecnologia—CNR, IFN, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyThe Photon Factory and School of Chemical Sciences, The University of Auckland, Auckland 1142, New ZealandDipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyDipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalySCITEC—CNR, Via A. Corti, 20133 Milano, ItalySCITEC—CNR, Via A. Corti, 20133 Milano, ItalyIstituto di Fotonica e Nanotecnologia—CNR, IFN, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyPhotonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the morphology (dimension) and optical properties (refractive index) of the building blocks. In this study, we report the fabrication and optical characterization of photonic glasses obtained via a self-assembling technique. Furthermore, we have demonstrated that the infiltration of these systems with a green-emitting polymer enhances the properties of the polymer, resulting in a large increase in its photoluminescence quantum yield and a 3 ps growing time of the photoluminescence time decay Finally, the development of the aforementioned system can serve as a suitable low-cost platform for the realization of lasers and fluorescence-based bio-sensors.https://www.mdpi.com/1420-3049/29/3/654photonic glassesquantum yieldF8BTphotoluminescence propertiesoptical features
spellingShingle Andrea Chiappini
Davide Faccialà
Nina I. Novikova
Samim Sardar
Cosimo D’Andrea
Guido Scavia
Chiara Botta
Tersilla Virgili
Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
Molecules
photonic glasses
quantum yield
F8BT
photoluminescence properties
optical features
title Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
title_full Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
title_fullStr Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
title_full_unstemmed Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
title_short Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
title_sort enhancement of photoluminescence properties via polymer infiltration in a colloidal photonic glass
topic photonic glasses
quantum yield
F8BT
photoluminescence properties
optical features
url https://www.mdpi.com/1420-3049/29/3/654
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