Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass
Photonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the...
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MDPI AG
2024-01-01
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Series: | Molecules |
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Online Access: | https://www.mdpi.com/1420-3049/29/3/654 |
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author | Andrea Chiappini Davide Faccialà Nina I. Novikova Samim Sardar Cosimo D’Andrea Guido Scavia Chiara Botta Tersilla Virgili |
author_facet | Andrea Chiappini Davide Faccialà Nina I. Novikova Samim Sardar Cosimo D’Andrea Guido Scavia Chiara Botta Tersilla Virgili |
author_sort | Andrea Chiappini |
collection | DOAJ |
description | Photonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the morphology (dimension) and optical properties (refractive index) of the building blocks. In this study, we report the fabrication and optical characterization of photonic glasses obtained via a self-assembling technique. Furthermore, we have demonstrated that the infiltration of these systems with a green-emitting polymer enhances the properties of the polymer, resulting in a large increase in its photoluminescence quantum yield and a 3 ps growing time of the photoluminescence time decay Finally, the development of the aforementioned system can serve as a suitable low-cost platform for the realization of lasers and fluorescence-based bio-sensors. |
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institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-08T03:51:30Z |
publishDate | 2024-01-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-31cda92bab134358a68a531fdf33f7922024-02-09T15:18:59ZengMDPI AGMolecules1420-30492024-01-0129365410.3390/molecules29030654Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic GlassAndrea Chiappini0Davide Faccialà1Nina I. Novikova2Samim Sardar3Cosimo D’Andrea4Guido Scavia5Chiara Botta6Tersilla Virgili7Istituto di Fotonica e Nanotecnologia—CNR, IFN and FBK Photonics Unit, Via alla Cascata 56/c, Povo, 38123 Trento, ItalyIstituto di Fotonica e Nanotecnologia—CNR, IFN, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyThe Photon Factory and School of Chemical Sciences, The University of Auckland, Auckland 1142, New ZealandDipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyDipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalySCITEC—CNR, Via A. Corti, 20133 Milano, ItalySCITEC—CNR, Via A. Corti, 20133 Milano, ItalyIstituto di Fotonica e Nanotecnologia—CNR, IFN, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyPhotonic glasses (PGs) based on the self-assembly of monosized nanoparticles can be an effective tool for realizing disordered structures capable of tailoring light diffusion due to the establishment of Mie resonances. In particular, the wavelength position of these resonances depends mainly on the morphology (dimension) and optical properties (refractive index) of the building blocks. In this study, we report the fabrication and optical characterization of photonic glasses obtained via a self-assembling technique. Furthermore, we have demonstrated that the infiltration of these systems with a green-emitting polymer enhances the properties of the polymer, resulting in a large increase in its photoluminescence quantum yield and a 3 ps growing time of the photoluminescence time decay Finally, the development of the aforementioned system can serve as a suitable low-cost platform for the realization of lasers and fluorescence-based bio-sensors.https://www.mdpi.com/1420-3049/29/3/654photonic glassesquantum yieldF8BTphotoluminescence propertiesoptical features |
spellingShingle | Andrea Chiappini Davide Faccialà Nina I. Novikova Samim Sardar Cosimo D’Andrea Guido Scavia Chiara Botta Tersilla Virgili Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass Molecules photonic glasses quantum yield F8BT photoluminescence properties optical features |
title | Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass |
title_full | Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass |
title_fullStr | Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass |
title_full_unstemmed | Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass |
title_short | Enhancement of Photoluminescence Properties via Polymer Infiltration in a Colloidal Photonic Glass |
title_sort | enhancement of photoluminescence properties via polymer infiltration in a colloidal photonic glass |
topic | photonic glasses quantum yield F8BT photoluminescence properties optical features |
url | https://www.mdpi.com/1420-3049/29/3/654 |
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