High-temperature graphitization characteristics of vitrinite and inertinite
In order to explore the graphitization characteristic differences between vitrinite and inertinite in coal, this study conducted high-temperature thermal simulation experiments (at five temperature points: 1800°C, 2100°C, 2400°C, 2700°C, and 3000°C) using inertinite-rich and vitrinite-rich samples a...
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Frontiers Media S.A.
2023-07-01
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| Series: | Frontiers in Earth Science |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/feart.2023.1235457/full |
| _version_ | 1797782948957650944 |
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| author | Liu Zhifei Liu Zhifei Cao Daiyong Chen Gaojian Chen Qingtong Bi Zhongwei |
| author_facet | Liu Zhifei Liu Zhifei Cao Daiyong Chen Gaojian Chen Qingtong Bi Zhongwei |
| author_sort | Liu Zhifei |
| collection | DOAJ |
| description | In order to explore the graphitization characteristic differences between vitrinite and inertinite in coal, this study conducted high-temperature thermal simulation experiments (at five temperature points: 1800°C, 2100°C, 2400°C, 2700°C, and 3000°C) using inertinite-rich and vitrinite-rich samples as graphitization precursors. The quantitative comparison for the evolution characteristics of their graphite lattice was carried out using high-resolution transmission electron microscopy (HRTEM), X-ray diffractometer (XRD), and Raman spectroscopy (Raman) techniques. HRTEM revealed that an evident increase in carbon layer numbers and degree of extension was observed with increasing treatment temperature, XRD showed the variation of lattice parameters (d002/La/Lc) with temperature, Raman data revealed the variation of lattice defects (R2/R3) with temperature. It was discussed about the differences of graphite lattice construction processes between inertinite and vitrinite, throughout the entire temperature range of the experiment, the d002 spacing of inertinite was always smaller than that of vitrinite, indicating a higher degree of graphitization. vitrinite exhibited a uniform and smooth evolution state throughout the entire heating process, while inertinite exhibited an “inert” state between 1800°C and 2100°C (d002 values stagnated near at 0.3440 nm). With increasing simulated temperature, the defect level (R2 and R3) of vitrinite rapidly decreased below that of inertinite, throughout the entire temperature range, vitrinite demonstrated superior defect healing ability in terms of both rate and capability compared to inertinite. Under high-temperature thermal simulation, the three-dimensional lattice construction and defect elimination of vitrinite exhibited synchronous evolution characteristics. On the other hand, the formation of the graphite lattice in inertinite showed an evolutionary trend of “first three-dimensional lattice construction, followed by gradual defect elimination”. |
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| institution | Directory Open Access Journal |
| issn | 2296-6463 |
| language | English |
| last_indexed | 2024-03-13T00:19:09Z |
| publishDate | 2023-07-01 |
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| series | Frontiers in Earth Science |
| spelling | doaj.art-31e00666e79a45d99dc0b892e84050862023-07-11T18:14:49ZengFrontiers Media S.A.Frontiers in Earth Science2296-64632023-07-011110.3389/feart.2023.12354571235457High-temperature graphitization characteristics of vitrinite and inertiniteLiu Zhifei0Liu Zhifei1Cao Daiyong2Chen Gaojian3Chen Qingtong4Bi Zhongwei5China Coal Technology and Engineering Group Corp, China Coal Research Institute, Beijing, ChinaChina University of Mining and Technology, Beijing, ChinaChina University of Mining and Technology, Beijing, ChinaChina University of Mining and Technology, Beijing, ChinaChina Coal Technology and Engineering Group Corp, China Coal Research Institute, Beijing, ChinaChina Coal Technology and Engineering Group Corp, China Coal Research Institute, Beijing, ChinaIn order to explore the graphitization characteristic differences between vitrinite and inertinite in coal, this study conducted high-temperature thermal simulation experiments (at five temperature points: 1800°C, 2100°C, 2400°C, 2700°C, and 3000°C) using inertinite-rich and vitrinite-rich samples as graphitization precursors. The quantitative comparison for the evolution characteristics of their graphite lattice was carried out using high-resolution transmission electron microscopy (HRTEM), X-ray diffractometer (XRD), and Raman spectroscopy (Raman) techniques. HRTEM revealed that an evident increase in carbon layer numbers and degree of extension was observed with increasing treatment temperature, XRD showed the variation of lattice parameters (d002/La/Lc) with temperature, Raman data revealed the variation of lattice defects (R2/R3) with temperature. It was discussed about the differences of graphite lattice construction processes between inertinite and vitrinite, throughout the entire temperature range of the experiment, the d002 spacing of inertinite was always smaller than that of vitrinite, indicating a higher degree of graphitization. vitrinite exhibited a uniform and smooth evolution state throughout the entire heating process, while inertinite exhibited an “inert” state between 1800°C and 2100°C (d002 values stagnated near at 0.3440 nm). With increasing simulated temperature, the defect level (R2 and R3) of vitrinite rapidly decreased below that of inertinite, throughout the entire temperature range, vitrinite demonstrated superior defect healing ability in terms of both rate and capability compared to inertinite. Under high-temperature thermal simulation, the three-dimensional lattice construction and defect elimination of vitrinite exhibited synchronous evolution characteristics. On the other hand, the formation of the graphite lattice in inertinite showed an evolutionary trend of “first three-dimensional lattice construction, followed by gradual defect elimination”.https://www.frontiersin.org/articles/10.3389/feart.2023.1235457/fullcoal-based graphitehigh-temperature thermal simulationvitriniteinertiniteX-ray diffraction |
| spellingShingle | Liu Zhifei Liu Zhifei Cao Daiyong Chen Gaojian Chen Qingtong Bi Zhongwei High-temperature graphitization characteristics of vitrinite and inertinite Frontiers in Earth Science coal-based graphite high-temperature thermal simulation vitrinite inertinite X-ray diffraction |
| title | High-temperature graphitization characteristics of vitrinite and inertinite |
| title_full | High-temperature graphitization characteristics of vitrinite and inertinite |
| title_fullStr | High-temperature graphitization characteristics of vitrinite and inertinite |
| title_full_unstemmed | High-temperature graphitization characteristics of vitrinite and inertinite |
| title_short | High-temperature graphitization characteristics of vitrinite and inertinite |
| title_sort | high temperature graphitization characteristics of vitrinite and inertinite |
| topic | coal-based graphite high-temperature thermal simulation vitrinite inertinite X-ray diffraction |
| url | https://www.frontiersin.org/articles/10.3389/feart.2023.1235457/full |
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