Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique

This paper was aimed to evaluate the polyurethane (PU) and polyurethane/polyvinyl chloride (90 wt. % / 10 wt. %) as organic coating of carbon steel substrate against marine environment (3.5 wt.% NaCl aqueous solution) as a severe corrosion environment . The electrochemical impedance spectroscopy (E...

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Main Author: Abdul-Karim M. A. Alsamuraee
Format: Article
Language:English
Published: University of Baghdad 2010-10-01
Series:Iraqi Journal of Physics
Subjects:
Online Access:https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/864
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author Abdul-Karim M. A. Alsamuraee
author_facet Abdul-Karim M. A. Alsamuraee
author_sort Abdul-Karim M. A. Alsamuraee
collection DOAJ
description This paper was aimed to evaluate the polyurethane (PU) and polyurethane/polyvinyl chloride (90 wt. % / 10 wt. %) as organic coating of carbon steel substrate against marine environment (3.5 wt.% NaCl aqueous solution) as a severe corrosion environment . The electrochemical impedance spectroscopy (EIS) and fitting impedance data by ZsimpWin 3.22 software were used to estimate the physical barrier of the samples for different exposure times. Different equivalent electrical circuits were proposed for the physical barrier at different immersion times to get appropriate fitting .Both PU and PU/PVC coatings showed excellent corrosion protection ability for steel .The PU/PVC coating showed better protection and stability than PU coating against aggressive salt solution. The relation between dielectric properties (impedance spectrum) of coating film with their behavior as physical barrier protection gave useful information about electrochemical process and predicts the barrier protective behavior in natural environment.
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spelling doaj.art-31e46c0a65b34107b37312b2e8aca9992023-03-14T05:49:04ZengUniversity of BaghdadIraqi Journal of Physics2070-40032664-55482010-10-01811Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS techniqueAbdul-Karim M. A. Alsamuraee0The Ministry of Science & Technology This paper was aimed to evaluate the polyurethane (PU) and polyurethane/polyvinyl chloride (90 wt. % / 10 wt. %) as organic coating of carbon steel substrate against marine environment (3.5 wt.% NaCl aqueous solution) as a severe corrosion environment . The electrochemical impedance spectroscopy (EIS) and fitting impedance data by ZsimpWin 3.22 software were used to estimate the physical barrier of the samples for different exposure times. Different equivalent electrical circuits were proposed for the physical barrier at different immersion times to get appropriate fitting .Both PU and PU/PVC coatings showed excellent corrosion protection ability for steel .The PU/PVC coating showed better protection and stability than PU coating against aggressive salt solution. The relation between dielectric properties (impedance spectrum) of coating film with their behavior as physical barrier protection gave useful information about electrochemical process and predicts the barrier protective behavior in natural environment. https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/864Corrosion protection Organic coating.
spellingShingle Abdul-Karim M. A. Alsamuraee
Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
Iraqi Journal of Physics
Corrosion protection Organic coating.
title Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
title_full Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
title_fullStr Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
title_full_unstemmed Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
title_short Evaluation of polyurethane and polyurethane /polyvinyl chloride blend coatings on steel as corrosion protection using EIS technique
title_sort evaluation of polyurethane and polyurethane polyvinyl chloride blend coatings on steel as corrosion protection using eis technique
topic Corrosion protection Organic coating.
url https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/864
work_keys_str_mv AT abdulkarimmaalsamuraee evaluationofpolyurethaneandpolyurethanepolyvinylchlorideblendcoatingsonsteelascorrosionprotectionusingeistechnique