Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II)
The molecule of the title compound, [Pb(C16H16NS2)2], is located on a twofold rotation axis, which runs through the PbII atom. The two dithiocarbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a di...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812036161 |
| _version_ | 1798025824182468608 |
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| author | E. Sathiyaraj S. Thirumaran S. Selvanayagam |
| author_facet | E. Sathiyaraj S. Thirumaran S. Selvanayagam |
| author_sort | E. Sathiyaraj |
| collection | DOAJ |
| description | The molecule of the title compound, [Pb(C16H16NS2)2], is located on a twofold rotation axis, which runs through the PbII atom. The two dithiocarbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The molecular conformation is stabilized by intramolecular C—H...S interactions. |
| first_indexed | 2024-04-11T18:25:08Z |
| format | Article |
| id | doaj.art-31f11cdd0c414f348b0bdb14575bb757 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:25:08Z |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-31f11cdd0c414f348b0bdb14575bb7572022-12-22T04:09:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1217m121710.1107/S1600536812036161Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II)E. SathiyarajS. ThirumaranS. SelvanayagamThe molecule of the title compound, [Pb(C16H16NS2)2], is located on a twofold rotation axis, which runs through the PbII atom. The two dithiocarbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The molecular conformation is stabilized by intramolecular C—H...S interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812036161 |
| spellingShingle | E. Sathiyaraj S. Thirumaran S. Selvanayagam Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) Acta Crystallographica Section E |
| title | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) |
| title_full | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) |
| title_fullStr | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) |
| title_full_unstemmed | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) |
| title_short | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]lead(II) |
| title_sort | bis n benzyl n 2 phenylethyl dithiocarbamato amp 954 2s s amp 8242 lead ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812036161 |
| work_keys_str_mv | AT esathiyaraj bisnbenzyln2phenylethyldithiocarbamatoamp9542ssamp8242leadii AT sthirumaran bisnbenzyln2phenylethyldithiocarbamatoamp9542ssamp8242leadii AT sselvanayagam bisnbenzyln2phenylethyldithiocarbamatoamp9542ssamp8242leadii |