Coordination Behavior of N2o Donor Ligand with Some Metalsions

Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H...

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Main Author: Ali M. A. Al-khazraji
Format: Article
Language:English
Published: University of Baghdad 2017-02-01
Series:Ibn Al-Haitham Journal for Pure and Applied Sciences
Subjects:
Online Access:https://jih.uobaghdad.edu.iq/index.php/j/article/view/19
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author Ali M. A. Al-khazraji
author_facet Ali M. A. Al-khazraji
author_sort Ali M. A. Al-khazraji
collection DOAJ
description Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H-&13C-NMR, UV-visible, FT-IR, (only ligand), molar conductance elemental, analysis and magnetic susceptibility, calculations. It has been set that the ligand acts as (N, N, O) neutral tridentate forming chelates with stoichimetry (metal: ligand) (1:1). all metal complexes is suggested Octahedral configuration. Most of the prepared compounds show antibacterial activity to (Staphylococcus aureus),(Escherichia coli), (Bacillussubtilis) and (Pseudomonas aeroginosa).
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spelling doaj.art-31fc086eb07c483e8539c00e66c74d402022-12-22T02:25:14ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-02-01293Coordination Behavior of N2o Donor Ligand with Some MetalsionsAli M. A. Al-khazraji Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H-&13C-NMR, UV-visible, FT-IR, (only ligand), molar conductance elemental, analysis and magnetic susceptibility, calculations. It has been set that the ligand acts as (N, N, O) neutral tridentate forming chelates with stoichimetry (metal: ligand) (1:1). all metal complexes is suggested Octahedral configuration. Most of the prepared compounds show antibacterial activity to (Staphylococcus aureus),(Escherichia coli), (Bacillussubtilis) and (Pseudomonas aeroginosa). https://jih.uobaghdad.edu.iq/index.php/j/article/view/19Schiff base, tridentate, Metal complexesand3-amino benzoic acid
spellingShingle Ali M. A. Al-khazraji
Coordination Behavior of N2o Donor Ligand with Some Metalsions
Ibn Al-Haitham Journal for Pure and Applied Sciences
Schiff base, tridentate, Metal complexesand3-amino benzoic acid
title Coordination Behavior of N2o Donor Ligand with Some Metalsions
title_full Coordination Behavior of N2o Donor Ligand with Some Metalsions
title_fullStr Coordination Behavior of N2o Donor Ligand with Some Metalsions
title_full_unstemmed Coordination Behavior of N2o Donor Ligand with Some Metalsions
title_short Coordination Behavior of N2o Donor Ligand with Some Metalsions
title_sort coordination behavior of n2o donor ligand with some metalsions
topic Schiff base, tridentate, Metal complexesand3-amino benzoic acid
url https://jih.uobaghdad.edu.iq/index.php/j/article/view/19
work_keys_str_mv AT alimaalkhazraji coordinationbehaviorofn2odonorligandwithsomemetalsions