Coordination Behavior of N2o Donor Ligand with Some Metalsions
Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H...
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Format: | Article |
Language: | English |
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University of Baghdad
2017-02-01
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Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
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Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/19 |
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author | Ali M. A. Al-khazraji |
author_facet | Ali M. A. Al-khazraji |
author_sort | Ali M. A. Al-khazraji |
collection | DOAJ |
description |
Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H-&13C-NMR, UV-visible, FT-IR, (only ligand), molar conductance elemental, analysis and magnetic susceptibility, calculations. It has been set that the ligand acts as (N, N, O) neutral tridentate forming chelates with stoichimetry (metal: ligand) (1:1). all metal complexes is suggested Octahedral configuration. Most of the prepared compounds show antibacterial activity to (Staphylococcus aureus),(Escherichia coli), (Bacillussubtilis) and (Pseudomonas aeroginosa).
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first_indexed | 2024-04-13T23:21:24Z |
format | Article |
id | doaj.art-31fc086eb07c483e8539c00e66c74d40 |
institution | Directory Open Access Journal |
issn | 1609-4042 2521-3407 |
language | English |
last_indexed | 2024-04-13T23:21:24Z |
publishDate | 2017-02-01 |
publisher | University of Baghdad |
record_format | Article |
series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
spelling | doaj.art-31fc086eb07c483e8539c00e66c74d402022-12-22T02:25:14ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-02-01293Coordination Behavior of N2o Donor Ligand with Some MetalsionsAli M. A. Al-khazraji Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H-&13C-NMR, UV-visible, FT-IR, (only ligand), molar conductance elemental, analysis and magnetic susceptibility, calculations. It has been set that the ligand acts as (N, N, O) neutral tridentate forming chelates with stoichimetry (metal: ligand) (1:1). all metal complexes is suggested Octahedral configuration. Most of the prepared compounds show antibacterial activity to (Staphylococcus aureus),(Escherichia coli), (Bacillussubtilis) and (Pseudomonas aeroginosa). https://jih.uobaghdad.edu.iq/index.php/j/article/view/19Schiff base, tridentate, Metal complexesand3-amino benzoic acid |
spellingShingle | Ali M. A. Al-khazraji Coordination Behavior of N2o Donor Ligand with Some Metalsions Ibn Al-Haitham Journal for Pure and Applied Sciences Schiff base, tridentate, Metal complexesand3-amino benzoic acid |
title | Coordination Behavior of N2o Donor Ligand with Some Metalsions |
title_full | Coordination Behavior of N2o Donor Ligand with Some Metalsions |
title_fullStr | Coordination Behavior of N2o Donor Ligand with Some Metalsions |
title_full_unstemmed | Coordination Behavior of N2o Donor Ligand with Some Metalsions |
title_short | Coordination Behavior of N2o Donor Ligand with Some Metalsions |
title_sort | coordination behavior of n2o donor ligand with some metalsions |
topic | Schiff base, tridentate, Metal complexesand3-amino benzoic acid |
url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/19 |
work_keys_str_mv | AT alimaalkhazraji coordinationbehaviorofn2odonorligandwithsomemetalsions |