Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions
In this study, the influence of microstructure and buffer system on the corrosion behaviour of Mg-1 wt. % Zn is examined. The grain size of the alloy was refined from 700 µm to under 15 µm by rolling with varying reduction percentages per pass. The effects of the rolling procedure on the resulting c...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-10-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/12/10/1491 |
| _version_ | 1797473993074147328 |
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| author | Ryan N. Wilkes George Dias Mark P. Staiger |
| author_facet | Ryan N. Wilkes George Dias Mark P. Staiger |
| author_sort | Ryan N. Wilkes |
| collection | DOAJ |
| description | In this study, the influence of microstructure and buffer system on the corrosion behaviour of Mg-1 wt. % Zn is examined. The grain size of the alloy was refined from 700 µm to under 15 µm by rolling with varying reduction percentages per pass. The effects of the rolling procedure on the resulting corrosion profile were analysed with immersion and electrochemical methods. Though the rolling procedure resulted in significant grain refinement, the as-cast samples had the lowest corrosion rate of 2.8 mm/yr, while those of the rolled samples were as high as 15.8 mm/yr. The HEPES buffer system did not control the pH or support the formation of insoluble precipitates as well as the NaHCO3/CO2 buffer system, leading to more severe localised pitting corrosion in samples immersed in HEPES buffered media. While reducing grain size generally corresponds to a lower corrosion rate in Mg alloys, this study provides evidence that other factors such as texture and buffer system must also be considered to accurately test candidate alloys for biodegradable orthopaedic applications. |
| first_indexed | 2024-03-09T20:24:03Z |
| format | Article |
| id | doaj.art-3215c921c2a747eaa959795edc20c58e |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T20:24:03Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-3215c921c2a747eaa959795edc20c58e2023-11-23T23:39:22ZengMDPI AGCrystals2073-43522022-10-011210149110.3390/cryst12101491Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure InteractionsRyan N. Wilkes0George Dias1Mark P. Staiger2Department of Mechanical Engineering, University of Canterbury, Private Bag 4800, Christchurch 8140, New ZealandDepartment of Anatomy and Structural Biology, University of Otago, Dunedin 9054, New ZealandDepartment of Mechanical Engineering, University of Canterbury, Private Bag 4800, Christchurch 8140, New ZealandIn this study, the influence of microstructure and buffer system on the corrosion behaviour of Mg-1 wt. % Zn is examined. The grain size of the alloy was refined from 700 µm to under 15 µm by rolling with varying reduction percentages per pass. The effects of the rolling procedure on the resulting corrosion profile were analysed with immersion and electrochemical methods. Though the rolling procedure resulted in significant grain refinement, the as-cast samples had the lowest corrosion rate of 2.8 mm/yr, while those of the rolled samples were as high as 15.8 mm/yr. The HEPES buffer system did not control the pH or support the formation of insoluble precipitates as well as the NaHCO3/CO2 buffer system, leading to more severe localised pitting corrosion in samples immersed in HEPES buffered media. While reducing grain size generally corresponds to a lower corrosion rate in Mg alloys, this study provides evidence that other factors such as texture and buffer system must also be considered to accurately test candidate alloys for biodegradable orthopaedic applications.https://www.mdpi.com/2073-4352/12/10/1491biodegradable magnesiumtexturebuffer |
| spellingShingle | Ryan N. Wilkes George Dias Mark P. Staiger Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions Crystals biodegradable magnesium texture buffer |
| title | Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions |
| title_full | Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions |
| title_fullStr | Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions |
| title_full_unstemmed | Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions |
| title_short | Anomalous In Vitro Corrosion Behaviour of Rolled Mg-1 wt. % Zn Alloy Due to Buffer-Microstructure Interactions |
| title_sort | anomalous in vitro corrosion behaviour of rolled mg 1 wt zn alloy due to buffer microstructure interactions |
| topic | biodegradable magnesium texture buffer |
| url | https://www.mdpi.com/2073-4352/12/10/1491 |
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