Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases
A series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basi...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2006-09-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol71/No8-9/JSCS_V71_No8-9-08.pdf |
| _version_ | 1818960012668567552 |
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| author | ANKITA SRIVASTAVA SHIPRA SRIVASTAVA |
| author_facet | ANKITA SRIVASTAVA SHIPRA SRIVASTAVA |
| author_sort | ANKITA SRIVASTAVA |
| collection | DOAJ |
| description | A series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basis of their elemental analyses, magnetic moment, conductance, IR, electronic, 1HNMR and FAB mass spectra, as well as thermal analyses. The Ru(III) complexes are low spin paramagnetic, while Rh(III) and Ir(III) behave as diamagnetic complexes. The IR spectral data revealed that all the Schiff bases behave as tetradentate and are coordinated to Ru(III), Rh(III) and Ir(III) via nitrogen and oxygen. Antifungal studies of the ligands as well as their complexes were carried out by the agar plate method. |
| first_indexed | 2024-12-20T11:50:46Z |
| format | Article |
| id | doaj.art-3218a52590444c4b8528cf7044d72425 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-20T11:50:46Z |
| publishDate | 2006-09-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-3218a52590444c4b8528cf7044d724252022-12-21T19:41:46ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392006-09-01718-9917928Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff basesANKITA SRIVASTAVASHIPRA SRIVASTAVAA series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basis of their elemental analyses, magnetic moment, conductance, IR, electronic, 1HNMR and FAB mass spectra, as well as thermal analyses. The Ru(III) complexes are low spin paramagnetic, while Rh(III) and Ir(III) behave as diamagnetic complexes. The IR spectral data revealed that all the Schiff bases behave as tetradentate and are coordinated to Ru(III), Rh(III) and Ir(III) via nitrogen and oxygen. Antifungal studies of the ligands as well as their complexes were carried out by the agar plate method.http://www.shd.org.yu/HtDocs/SHD/Vol71/No8-9/JSCS_V71_No8-9-08.pdfRu(III)Rh(III)Ir(III)complexesSchiff basespectral and antifungal studies |
| spellingShingle | ANKITA SRIVASTAVA SHIPRA SRIVASTAVA Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases Journal of the Serbian Chemical Society Ru(III) Rh(III) Ir(III) complexes Schiff base spectral and antifungal studies |
| title | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases |
| title_full | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases |
| title_fullStr | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases |
| title_full_unstemmed | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases |
| title_short | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate Schiff bases |
| title_sort | synthetic structural and antifungal studies of coordination compounds of ru iii rh iii and ir iii with tetradentate schiff bases |
| topic | Ru(III) Rh(III) Ir(III) complexes Schiff base spectral and antifungal studies |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol71/No8-9/JSCS_V71_No8-9-08.pdf |
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