SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure
Single crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 °C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental compo...
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| Format: | Article |
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MDPI AG
2022-09-01
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| Online Access: | https://www.mdpi.com/2073-4352/12/10/1360 |
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| author | Liurukara D. Sanjeewa Tiffany M. Smith Pellizzeri Colin D. McMillen Keith Taddei Thomas Heitmann Helmut Kaiser Joseph W. Kolis |
| author_facet | Liurukara D. Sanjeewa Tiffany M. Smith Pellizzeri Colin D. McMillen Keith Taddei Thomas Heitmann Helmut Kaiser Joseph W. Kolis |
| author_sort | Liurukara D. Sanjeewa |
| collection | DOAJ |
| description | Single crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 °C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental composition, respectively. SrNi(VO<sub>4</sub>)(OH) crystallizes in an acentric orthorhombic crystal system in the space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> (no. 19); <i>Z</i> = 4, <i>a</i> = 5.9952(4) Å, <i>b</i> = 7.5844(4) Å, <i>c</i> = 9.2240(5) Å. The structure is comprised of a Ni–O–V framework where Sr<sup>2+</sup> ions reside inside the channels. Single-crystal magnetic measurements display a significant anisotropy in both temperature- and field-dependent data. The temperature dependent magnetic measurement shows antiferromagnetic behavior at <i>T</i><sub>N</sub>~8 K. Overall, the magnetic properties indicate the presence of competing antiferromagnetic and ferromagnetic interactions of SrNi(VO<sub>4</sub>)(OH). |
| first_indexed | 2024-03-09T20:25:03Z |
| format | Article |
| id | doaj.art-321d9c528da54d8d974323802e7b11b1 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T20:25:03Z |
| publishDate | 2022-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-321d9c528da54d8d974323802e7b11b12023-11-23T23:37:11ZengMDPI AGCrystals2073-43522022-09-011210136010.3390/cryst12101360SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type StructureLiurukara D. Sanjeewa0Tiffany M. Smith Pellizzeri1Colin D. McMillen2Keith Taddei3Thomas Heitmann4Helmut Kaiser5Joseph W. Kolis6University of Missouri Research Reactor (MURR), University of Missouri, Columbia, MO 65211, USADepartment of Chemistry and Biochemistry, Eastern Illinois University, Charleston, IL 61920, USADepartment of Chemistry, Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, Clemson, SC 29634, USANeutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USAUniversity of Missouri Research Reactor (MURR), University of Missouri, Columbia, MO 65211, USAUniversity of Missouri Research Reactor (MURR), University of Missouri, Columbia, MO 65211, USADepartment of Chemistry, Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, Clemson, SC 29634, USASingle crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 °C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental composition, respectively. SrNi(VO<sub>4</sub>)(OH) crystallizes in an acentric orthorhombic crystal system in the space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> (no. 19); <i>Z</i> = 4, <i>a</i> = 5.9952(4) Å, <i>b</i> = 7.5844(4) Å, <i>c</i> = 9.2240(5) Å. The structure is comprised of a Ni–O–V framework where Sr<sup>2+</sup> ions reside inside the channels. Single-crystal magnetic measurements display a significant anisotropy in both temperature- and field-dependent data. The temperature dependent magnetic measurement shows antiferromagnetic behavior at <i>T</i><sub>N</sub>~8 K. Overall, the magnetic properties indicate the presence of competing antiferromagnetic and ferromagnetic interactions of SrNi(VO<sub>4</sub>)(OH).https://www.mdpi.com/2073-4352/12/10/1360hydrothermalvanadatesnickel(II)antiferomagnetism |
| spellingShingle | Liurukara D. Sanjeewa Tiffany M. Smith Pellizzeri Colin D. McMillen Keith Taddei Thomas Heitmann Helmut Kaiser Joseph W. Kolis SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure Crystals hydrothermal vanadates nickel(II) antiferomagnetism |
| title | SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure |
| title_full | SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure |
| title_fullStr | SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure |
| title_full_unstemmed | SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure |
| title_short | SrNi(VO<sub>4</sub>)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure |
| title_sort | srni vo sub 4 sub oh the high temperature hydrothermal synthesis and magnetic properties of an adelite descloizite type structure |
| topic | hydrothermal vanadates nickel(II) antiferomagnetism |
| url | https://www.mdpi.com/2073-4352/12/10/1360 |
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