Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds
Transformations of alcohols, which are ubiquitous in chemistry and are native functionalities in many natural products and bioactive molecules, are cornerstones of organic synthesis. Here the authors describe photocatalyzed cross-couplings of activated alcohols with α-amino acids, providing a direct...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35249-7 |
| _version_ | 1797985532296298496 |
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| author | Yiman Gao Jie Liu Cong Wei Yan Li Kui Zhang Liangliang Song Lingchao Cai |
| author_facet | Yiman Gao Jie Liu Cong Wei Yan Li Kui Zhang Liangliang Song Lingchao Cai |
| author_sort | Yiman Gao |
| collection | DOAJ |
| description | Transformations of alcohols, which are ubiquitous in chemistry and are native functionalities in many natural products and bioactive molecules, are cornerstones of organic synthesis. Here the authors describe photocatalyzed cross-couplings of activated alcohols with α-amino acids, providing a direct approach for a variety of unnatural amino acids. |
| first_indexed | 2024-04-11T07:18:33Z |
| format | Article |
| id | doaj.art-32447fde2dea4acf8dd043f3f46ffe6b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-11T07:18:33Z |
| publishDate | 2022-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-32447fde2dea4acf8dd043f3f46ffe6b2022-12-22T04:37:49ZengNature PortfolioNature Communications2041-17232022-12-011311910.1038/s41467-022-35249-7Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bondsYiman Gao0Jie Liu1Cong Wei2Yan Li3Kui Zhang4Liangliang Song5Lingchao Cai6Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry UniversityTransformations of alcohols, which are ubiquitous in chemistry and are native functionalities in many natural products and bioactive molecules, are cornerstones of organic synthesis. Here the authors describe photocatalyzed cross-couplings of activated alcohols with α-amino acids, providing a direct approach for a variety of unnatural amino acids.https://doi.org/10.1038/s41467-022-35249-7 |
| spellingShingle | Yiman Gao Jie Liu Cong Wei Yan Li Kui Zhang Liangliang Song Lingchao Cai Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds Nature Communications |
| title | Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds |
| title_full | Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds |
| title_fullStr | Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds |
| title_full_unstemmed | Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds |
| title_short | Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds |
| title_sort | photoinduced β fragmentation of aliphatic alcohol derivatives for forging c c bonds |
| url | https://doi.org/10.1038/s41467-022-35249-7 |
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