Oil Identification of harp seal and other select marine mammals

Because of the rich omega-3 fatty acids content, harp seal (Pagophilus groenlandicus) oil is a popular supplement that is packaged as pills in Canada and sold for medicinal purposes, although this practice is banned in the United States. Due to US regulations, it is important to be able to distingui...

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Main Authors: Megahn H. Pinedo, Deborah A. Duffield, Dalin N. D’Alessandro, Erin R. Price, Edgard O. Espinoza
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Forensic Science International: Animals and Environments
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666937424000039
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author Megahn H. Pinedo
Deborah A. Duffield
Dalin N. D’Alessandro
Erin R. Price
Edgard O. Espinoza
author_facet Megahn H. Pinedo
Deborah A. Duffield
Dalin N. D’Alessandro
Erin R. Price
Edgard O. Espinoza
author_sort Megahn H. Pinedo
collection DOAJ
description Because of the rich omega-3 fatty acids content, harp seal (Pagophilus groenlandicus) oil is a popular supplement that is packaged as pills in Canada and sold for medicinal purposes, although this practice is banned in the United States. Due to US regulations, it is important to be able to distinguish between fish oil and seal oil, but the taxonomic determination of oils provenance has been a difficult problem to solve. In this study, Direct Analysis in Real Time time-of-flight mass spectrometry (DART TOFMS) was used to analyze the chemotypes of blubber samples collected from seven species of marine mammals, including seals, sea lions, and a porpoise. Results indicated that the chemotype profiles found in negative-ion mode could be used to separate all of the species using Discriminant Analysis of Principal Components (DAPC). Consequently, this study suggests that it may be possible to identify the taxonomic source of marine mammal oils based on chemical chemotypes.
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spelling doaj.art-325f9ed3781242798757e362f11d5b022024-06-21T08:58:00ZengElsevierForensic Science International: Animals and Environments2666-93742024-06-015100083Oil Identification of harp seal and other select marine mammalsMegahn H. Pinedo0Deborah A. Duffield1Dalin N. D’Alessandro2Erin R. Price3Edgard O. Espinoza4US Forest Service International Programs Wood Identification and Screening Center, Ashland , OR, USADepartment of Biology, Portland State University, Portland, OR, USADepartment of Biology, Portland State University, Portland, OR, USAUS Forest Service International Programs Wood Identification and Screening Center, Ashland , OR, USAUS National Fish and Wildlife Forensic Laboratory, Ashland, OR, USA; Corresponding author.Because of the rich omega-3 fatty acids content, harp seal (Pagophilus groenlandicus) oil is a popular supplement that is packaged as pills in Canada and sold for medicinal purposes, although this practice is banned in the United States. Due to US regulations, it is important to be able to distinguish between fish oil and seal oil, but the taxonomic determination of oils provenance has been a difficult problem to solve. In this study, Direct Analysis in Real Time time-of-flight mass spectrometry (DART TOFMS) was used to analyze the chemotypes of blubber samples collected from seven species of marine mammals, including seals, sea lions, and a porpoise. Results indicated that the chemotype profiles found in negative-ion mode could be used to separate all of the species using Discriminant Analysis of Principal Components (DAPC). Consequently, this study suggests that it may be possible to identify the taxonomic source of marine mammal oils based on chemical chemotypes.http://www.sciencedirect.com/science/article/pii/S2666937424000039Marine mammalBlubberOilForensicDARTChemotaxonomy
spellingShingle Megahn H. Pinedo
Deborah A. Duffield
Dalin N. D’Alessandro
Erin R. Price
Edgard O. Espinoza
Oil Identification of harp seal and other select marine mammals
Forensic Science International: Animals and Environments
Marine mammal
Blubber
Oil
Forensic
DART
Chemotaxonomy
title Oil Identification of harp seal and other select marine mammals
title_full Oil Identification of harp seal and other select marine mammals
title_fullStr Oil Identification of harp seal and other select marine mammals
title_full_unstemmed Oil Identification of harp seal and other select marine mammals
title_short Oil Identification of harp seal and other select marine mammals
title_sort oil identification of harp seal and other select marine mammals
topic Marine mammal
Blubber
Oil
Forensic
DART
Chemotaxonomy
url http://www.sciencedirect.com/science/article/pii/S2666937424000039
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