catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′]

catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′]

The Ni atom in the title linear supramolecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octahedral donor set defined by two symmetrically coordinating dithiophosphate ligands and pyridine N atoms derived from two bridging bis(4-pyridylmethylene)diazane ligands. The Ni atom l...

Full description

Bibliographic Details
Main Authors: Erick Berdugo, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809043505
Description
Summary:The Ni atom in the title linear supramolecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octahedral donor set defined by two symmetrically coordinating dithiophosphate ligands and pyridine N atoms derived from two bridging bis(4-pyridylmethylene)diazane ligands. The Ni atom lies on a centre of inversion and the bis(4-pyridylmethylene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H...S contacts and interdigitate with neighbouring layers, forming the crystal structure.
ISSN:1600-5368

Similar Items