catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′]
The Ni atom in the title linear supramolecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octahedral donor set defined by two symmetrically coordinating dithiophosphate ligands and pyridine N atoms derived from two bridging bis(4-pyridylmethylene)diazane ligands. The Ni atom l...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809043505 |
| _version_ | 1818791665267113984 |
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| author | Erick Berdugo Edward R. T. Tiekink |
| author_facet | Erick Berdugo Edward R. T. Tiekink |
| author_sort | Erick Berdugo |
| collection | DOAJ |
| description | The Ni atom in the title linear supramolecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octahedral donor set defined by two symmetrically coordinating dithiophosphate ligands and pyridine N atoms derived from two bridging bis(4-pyridylmethylene)diazane ligands. The Ni atom lies on a centre of inversion and the bis(4-pyridylmethylene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H...S contacts and interdigitate with neighbouring layers, forming the crystal structure. |
| first_indexed | 2024-12-18T15:14:58Z |
| format | Article |
| id | doaj.art-32692edfc643451588fd47f38a1b291f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:14:58Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-32692edfc643451588fd47f38a1b291f2022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1444m144510.1107/S1600536809043505catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′]Erick BerdugoEdward R. T. TiekinkThe Ni atom in the title linear supramolecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octahedral donor set defined by two symmetrically coordinating dithiophosphate ligands and pyridine N atoms derived from two bridging bis(4-pyridylmethylene)diazane ligands. The Ni atom lies on a centre of inversion and the bis(4-pyridylmethylene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H...S contacts and interdigitate with neighbouring layers, forming the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809043505 |
| spellingShingle | Erick Berdugo Edward R. T. Tiekink catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] Acta Crystallographica Section E |
| title | catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] |
| title_full | catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] |
| title_fullStr | catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] |
| title_full_unstemmed | catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] |
| title_short | catena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2N:N′] |
| title_sort | catena poly bis o o amp 8242 diisopropyl dithiophosphato amp 954 2s s amp 8242 nickel ii amp 956 bis 4 pyridylmethylene diazane amp 954 2n n amp 8242 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809043505 |
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