Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale

Abstract Herein, a KFeS2 whisker was formed in mass production at a low temperature, with waste cold-rolling sludge as Fe source, which exhibited good performance in the removal of Zn/Ni from real electroplating effluent. At laboratory scale, KFeS2 was generated at 80 °C by the hydrothermal method,...

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Main Authors: Dongxu Liang, Yu Chen, Suiyi Zhu, Yidi Gao, Tong Sun, Kyonghun Ri, Xinfeng Xie
Format: Article
Language:English
Published: BMC 2021-07-01
Series:Sustainable Environment Research
Subjects:
Online Access:https://doi.org/10.1186/s42834-021-00098-4
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author Dongxu Liang
Yu Chen
Suiyi Zhu
Yidi Gao
Tong Sun
Kyonghun Ri
Xinfeng Xie
author_facet Dongxu Liang
Yu Chen
Suiyi Zhu
Yidi Gao
Tong Sun
Kyonghun Ri
Xinfeng Xie
author_sort Dongxu Liang
collection DOAJ
description Abstract Herein, a KFeS2 whisker was formed in mass production at a low temperature, with waste cold-rolling sludge as Fe source, which exhibited good performance in the removal of Zn/Ni from real electroplating effluent. At laboratory scale, KFeS2 was generated at 80 °C by the hydrothermal method, and KFeS2 whisker grew radially with the extension of the reaction time. This method was applied at pilot scale, where a similar KFeS2 whisker was also produced with waste cold-rolling sludge as Fe source, and a residual brownish supernatant was observed after the reaction and then completely recycled in the next round for KFeS2 synthesis. After recycling five times, the produced KFeS2 whisker did not change. The drying and storage of KFeS2 have also been verified. Freeze drying and vacuum drying were applicable, whereas air drying was not profitable. Moreover, the efficiency of Zn/Ni removal using undried KFeS2 was similar to that of dried KFeS2. The efficiencies of Zn/Ni removal using KFeS2 were apparently higher those of common reagents for wastewater treatment.
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spelling doaj.art-32716b6b026443f1b2d4377aaa62a0192022-12-21T19:59:29ZengBMCSustainable Environment Research2468-20392021-07-0131111210.1186/s42834-021-00098-4Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scaleDongxu Liang0Yu Chen1Suiyi Zhu2Yidi Gao3Tong Sun4Kyonghun Ri5Xinfeng Xie6Science and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversityScience and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversityScience and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversityScience and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversityScience and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversityScience and Technology Innovation Center for Municipal Wastewater Treatment and Water Quality Protection, Northeast Normal UniversitySchool of Forest Resources and Environmental Science, Michigan Technological UniversityAbstract Herein, a KFeS2 whisker was formed in mass production at a low temperature, with waste cold-rolling sludge as Fe source, which exhibited good performance in the removal of Zn/Ni from real electroplating effluent. At laboratory scale, KFeS2 was generated at 80 °C by the hydrothermal method, and KFeS2 whisker grew radially with the extension of the reaction time. This method was applied at pilot scale, where a similar KFeS2 whisker was also produced with waste cold-rolling sludge as Fe source, and a residual brownish supernatant was observed after the reaction and then completely recycled in the next round for KFeS2 synthesis. After recycling five times, the produced KFeS2 whisker did not change. The drying and storage of KFeS2 have also been verified. Freeze drying and vacuum drying were applicable, whereas air drying was not profitable. Moreover, the efficiency of Zn/Ni removal using undried KFeS2 was similar to that of dried KFeS2. The efficiencies of Zn/Ni removal using KFeS2 were apparently higher those of common reagents for wastewater treatment.https://doi.org/10.1186/s42834-021-00098-4KFeS2 whiskerLow-temperature hydrothermal conversionPilot scaleTreatment of electroplating effluent
spellingShingle Dongxu Liang
Yu Chen
Suiyi Zhu
Yidi Gao
Tong Sun
Kyonghun Ri
Xinfeng Xie
Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
Sustainable Environment Research
KFeS2 whisker
Low-temperature hydrothermal conversion
Pilot scale
Treatment of electroplating effluent
title Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
title_full Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
title_fullStr Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
title_full_unstemmed Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
title_short Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale
title_sort low temperature conversion of fe rich sludge to kfes2 whisker a new flocculant synthesis from laboratory scale to pilot scale
topic KFeS2 whisker
Low-temperature hydrothermal conversion
Pilot scale
Treatment of electroplating effluent
url https://doi.org/10.1186/s42834-021-00098-4
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