Unconventional precipitation and martensitic transformation behaviour of Ni-rich NiTi alloy fabricated via laser-directed energy deposition

In this study, we report an unconventional precipitation and martensitic transformation behaviour of directly aged Ni-rich NiTi alloys fabricated via laser-directed energy deposition (LDED). Ni4Ti3 particles precipitate uniformly under all ageing conditions and no traditional multiple-step martensit...

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Bibliographic Details
Main Authors: Jingtao Kang, Ruidi Li, Dan Zheng, Huiting Wu, Minbo Wang, Pengda Niu, Jian Li, Xinyan Liu, Duan Lai, Tiechui Yuan
Format: Article
Language:English
Published: Taylor & Francis Group 2023-12-01
Series:Virtual and Physical Prototyping
Subjects:
Online Access:http://dx.doi.org/10.1080/17452759.2023.2231415
Description
Summary:In this study, we report an unconventional precipitation and martensitic transformation behaviour of directly aged Ni-rich NiTi alloys fabricated via laser-directed energy deposition (LDED). Ni4Ti3 particles precipitate uniformly under all ageing conditions and no traditional multiple-step martensitic transformations are observed. We conclude this unique behaviour to the intrinsic characteristics of the LDED technique, which are metastable microstructures and high residual stresses. On the one hand, these features make grain boundaries no longer a fevered location for precipitation and, on the other hand, significantly suppress the martensitic transformation when ageing at low temperatures (300°C/400°C). As the aging temperature increase (500°C), residual stresses release significantly, accompanied by the growth of Ni4Ti3 precipitates from several nanometres to 452 ± 181 nm with increased interparticle spacing. At the same time, reverse martensitic transformations change from two-step (B19′ → R → B2) to single-step (B19′ → B2).
ISSN:1745-2759
1745-2767