Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater

Considering sustainable mining, the use of seawater in mineral processing to replace conventional water is an attractive alternative, especially in cases where this resource is limited. However, the use of this aqueous medium generates a series of challenges; specifically, in the seawater flotation...

Full description

Bibliographic Details
Main Authors: Felipe Arcos, Lina Uribe
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Recycling
Subjects:
Online Access:https://www.mdpi.com/2313-4321/6/1/5
_version_ 1797413439979651072
author Felipe Arcos
Lina Uribe
author_facet Felipe Arcos
Lina Uribe
author_sort Felipe Arcos
collection DOAJ
description Considering sustainable mining, the use of seawater in mineral processing to replace conventional water is an attractive alternative, especially in cases where this resource is limited. However, the use of this aqueous medium generates a series of challenges; specifically, in the seawater flotation process, it is necessary to adapt traditional reagents to the aqueous medium or to propose new reagents that achieve better performance and are environmentally friendly. In this research, the technical feasibility of using recycled vegetable oil (RVO) as a collector of copper sulfide minerals in the flotation process using seawater was studied. The study considered the analysis of the metallurgical indexes when different concentrations of collector and foaming reagent were used, considering as collectors the RVO, potassium amyl xanthate (PAX) and mixtures of these, in addition to the methyl isobutyl carbinol (MIBC) as foaming agent. In addition, it was evidenced that the best metallurgical indexes were achieved using 40 g/t of RVO and 15 g/t of MIBC, which corresponded to an enrichment ratio of 6.29, a concentration ratio of 7.01, a copper recovery of 90.06% and a selectivity index with respect to pyrite of 4.03 and with respect to silica of 12.89. Finally, in relation to the study of the RVO and PAX collector mixtures, it was found that a mixture of 60 g/t of RVO and 40 g/t of PAX in the absence of foaming agent presented the best results in terms of copper recovery (98.66%) and the selectivity index with respect to pyrite (2.88) and silica (14.65), improving PAX selectivity and recovery compared to the use of RVO as the only collector. According to these results, it is possible to conclude that the addition of RVO improved the selectivity in the rougher flotation for copper sulfides in seawater. This could be an interesting opportunity for the industry to minimize the costs of the flotation process and generate a lower environmental impact.
first_indexed 2024-03-09T05:17:57Z
format Article
id doaj.art-32c5ccb45f7e40fba000b2a7293902fb
institution Directory Open Access Journal
issn 2313-4321
language English
last_indexed 2024-03-09T05:17:57Z
publishDate 2021-01-01
publisher MDPI AG
record_format Article
series Recycling
spelling doaj.art-32c5ccb45f7e40fba000b2a7293902fb2023-12-03T12:43:17ZengMDPI AGRecycling2313-43212021-01-01615010.3390/recycling6010005Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using SeawaterFelipe Arcos0Lina Uribe1School of Mining Engineering, University of Talca, Talca 3460000, ChileSchool of Mining Engineering, University of Talca, Talca 3460000, ChileConsidering sustainable mining, the use of seawater in mineral processing to replace conventional water is an attractive alternative, especially in cases where this resource is limited. However, the use of this aqueous medium generates a series of challenges; specifically, in the seawater flotation process, it is necessary to adapt traditional reagents to the aqueous medium or to propose new reagents that achieve better performance and are environmentally friendly. In this research, the technical feasibility of using recycled vegetable oil (RVO) as a collector of copper sulfide minerals in the flotation process using seawater was studied. The study considered the analysis of the metallurgical indexes when different concentrations of collector and foaming reagent were used, considering as collectors the RVO, potassium amyl xanthate (PAX) and mixtures of these, in addition to the methyl isobutyl carbinol (MIBC) as foaming agent. In addition, it was evidenced that the best metallurgical indexes were achieved using 40 g/t of RVO and 15 g/t of MIBC, which corresponded to an enrichment ratio of 6.29, a concentration ratio of 7.01, a copper recovery of 90.06% and a selectivity index with respect to pyrite of 4.03 and with respect to silica of 12.89. Finally, in relation to the study of the RVO and PAX collector mixtures, it was found that a mixture of 60 g/t of RVO and 40 g/t of PAX in the absence of foaming agent presented the best results in terms of copper recovery (98.66%) and the selectivity index with respect to pyrite (2.88) and silica (14.65), improving PAX selectivity and recovery compared to the use of RVO as the only collector. According to these results, it is possible to conclude that the addition of RVO improved the selectivity in the rougher flotation for copper sulfides in seawater. This could be an interesting opportunity for the industry to minimize the costs of the flotation process and generate a lower environmental impact.https://www.mdpi.com/2313-4321/6/1/5flotationseawatercollectorsvegetable oilrecycled vegetable oil
spellingShingle Felipe Arcos
Lina Uribe
Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
Recycling
flotation
seawater
collectors
vegetable oil
recycled vegetable oil
title Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
title_full Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
title_fullStr Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
title_full_unstemmed Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
title_short Evaluation of the Use of Recycled Vegetable Oil as a Collector Reagent in the Flotation of Copper Sulfide Minerals Using Seawater
title_sort evaluation of the use of recycled vegetable oil as a collector reagent in the flotation of copper sulfide minerals using seawater
topic flotation
seawater
collectors
vegetable oil
recycled vegetable oil
url https://www.mdpi.com/2313-4321/6/1/5
work_keys_str_mv AT felipearcos evaluationoftheuseofrecycledvegetableoilasacollectorreagentintheflotationofcoppersulfidemineralsusingseawater
AT linauribe evaluationoftheuseofrecycledvegetableoilasacollectorreagentintheflotationofcoppersulfidemineralsusingseawater