Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5

In the current investigation, we studied the influence of reaction conditions on the liquid products formation and catalysts stability in methanol to gasoline synthesis process. Methanol to gasoline synthesis was carried out in continuous mode regime. Main reaction products were found to be gases in...

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Main Authors: Valentin Doluda, Natalia Lakina, Alexander Sidorov, Antonina Stepacheva, Valentina Matveeva, Mikhail G. Sulman, Esther Sulman
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2018-08-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/657
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author Valentin Doluda
Natalia Lakina
Alexander Sidorov
Antonina Stepacheva
Valentina Matveeva
Mikhail G. Sulman
Esther Sulman
author_facet Valentin Doluda
Natalia Lakina
Alexander Sidorov
Antonina Stepacheva
Valentina Matveeva
Mikhail G. Sulman
Esther Sulman
author_sort Valentin Doluda
collection DOAJ
description In the current investigation, we studied the influence of reaction conditions on the liquid products formation and catalysts stability in methanol to gasoline synthesis process. Methanol to gasoline synthesis was carried out in continuous mode regime. Main reaction products were found to be gases including methane, ethylene, propylene, isobutene, and liquid hydrocarbons including cyclopropane and methylcyclopropane, as well as the aromatics - benzene, toluene, xylene, cresol, durol, naphthalene, methylnaphthalene, ethylnaphthalene, isopropylnaphthalene, methylisopropylnaphthalene etc. The optimal reaction conditions were found to be as the following: 5 bar of the total pressure in the system, 330 ºС process temperature, and methanol feed rate 5 mL/min. The optimal reactor size was found to be 30 cm length and 5 mm diameter. Under the established conditions the yield of the liquid strained hydrocarbons was the maximal and reached about 35 wt. %, while the aromatic content was only 3 wt. %.
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spelling doaj.art-32c7d673c73a4b04805c3088bdeade622022-12-21T20:18:13ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162018-08-017010.3303/CET1870227Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5Valentin DoludaNatalia LakinaAlexander SidorovAntonina StepachevaValentina MatveevaMikhail G. SulmanEsther SulmanIn the current investigation, we studied the influence of reaction conditions on the liquid products formation and catalysts stability in methanol to gasoline synthesis process. Methanol to gasoline synthesis was carried out in continuous mode regime. Main reaction products were found to be gases including methane, ethylene, propylene, isobutene, and liquid hydrocarbons including cyclopropane and methylcyclopropane, as well as the aromatics - benzene, toluene, xylene, cresol, durol, naphthalene, methylnaphthalene, ethylnaphthalene, isopropylnaphthalene, methylisopropylnaphthalene etc. The optimal reaction conditions were found to be as the following: 5 bar of the total pressure in the system, 330 ºС process temperature, and methanol feed rate 5 mL/min. The optimal reactor size was found to be 30 cm length and 5 mm diameter. Under the established conditions the yield of the liquid strained hydrocarbons was the maximal and reached about 35 wt. %, while the aromatic content was only 3 wt. %.https://www.cetjournal.it/index.php/cet/article/view/657
spellingShingle Valentin Doluda
Natalia Lakina
Alexander Sidorov
Antonina Stepacheva
Valentina Matveeva
Mikhail G. Sulman
Esther Sulman
Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
Chemical Engineering Transactions
title Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
title_full Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
title_fullStr Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
title_full_unstemmed Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
title_short Influence of the Reactor System on the Transformation of Methanol to Gasoline over H-ZSM-5
title_sort influence of the reactor system on the transformation of methanol to gasoline over h zsm 5
url https://www.cetjournal.it/index.php/cet/article/view/657
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