Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions

Hickory and peanut hydrochars were chemically activated with KOH and H3PO4 and tested for their ability to remove methylene blue and lead from aqueous solutions. The physicochemical characteristics of the activated hydrochars determined were surface area, pore volume, and elemental composition. Kine...

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Main Authors: June Fang, Bin Gao, Ahmed Mosa, Lu Zhan
Format: Article
Language:English
Published: Taylor & Francis Group 2017-01-01
Series:Chemical Speciation & Bioavailability
Subjects:
Online Access:http://dx.doi.org/10.1080/09542299.2017.1403294
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author June Fang
Bin Gao
Ahmed Mosa
Lu Zhan
author_facet June Fang
Bin Gao
Ahmed Mosa
Lu Zhan
author_sort June Fang
collection DOAJ
description Hickory and peanut hydrochars were chemically activated with KOH and H3PO4 and tested for their ability to remove methylene blue and lead from aqueous solutions. The physicochemical characteristics of the activated hydrochars determined were surface area, pore volume, and elemental composition. Kinetics and isotherm studies were then conducted on methylene blue adsorption. Compared to their nonactivated counterparts, the chemically activated hydrochars had higher surface areas and more functional groups. Activated hydrochars also had greater methylene blue and lead adsorption rates, which can be attributed to the improved physicochemical characteristics. H3PO4 activated hydrochars removed more contaminants than the corresponding KOH ones.
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spelling doaj.art-32d70de1128349b589237cd23dc9f9e52022-12-22T01:12:25ZengTaylor & Francis GroupChemical Speciation & Bioavailability0954-22992047-65232017-01-0129119720410.1080/09542299.2017.14032941403294Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutionsJune Fang0Bin Gao1Ahmed Mosa2Lu Zhan3University of FloridaUniversity of FloridaUniversity of FloridaUniversity of FloridaHickory and peanut hydrochars were chemically activated with KOH and H3PO4 and tested for their ability to remove methylene blue and lead from aqueous solutions. The physicochemical characteristics of the activated hydrochars determined were surface area, pore volume, and elemental composition. Kinetics and isotherm studies were then conducted on methylene blue adsorption. Compared to their nonactivated counterparts, the chemically activated hydrochars had higher surface areas and more functional groups. Activated hydrochars also had greater methylene blue and lead adsorption rates, which can be attributed to the improved physicochemical characteristics. H3PO4 activated hydrochars removed more contaminants than the corresponding KOH ones.http://dx.doi.org/10.1080/09542299.2017.1403294Activated carbonactivationadsorptionheavy metalsorganic pollutants
spellingShingle June Fang
Bin Gao
Ahmed Mosa
Lu Zhan
Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
Chemical Speciation & Bioavailability
Activated carbon
activation
adsorption
heavy metals
organic pollutants
title Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
title_full Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
title_fullStr Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
title_full_unstemmed Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
title_short Chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
title_sort chemical activation of hickory and peanut hull hydrochars for removal of lead and methylene blue from aqueous solutions
topic Activated carbon
activation
adsorption
heavy metals
organic pollutants
url http://dx.doi.org/10.1080/09542299.2017.1403294
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