Tuning the structural and optical properties of gold/silver nanoalloys prepared by laser ablation in liquids for ultra-sensitive spectroscopy and optical trapping
The plasmon resonance of metallic Au/Ag alloys in the colloidal state was tuned from 400 nm to 500 nm using a laser irradiated technique, performed directly in the liquid state. Interesting optical nonlinearities, trapping effects and spectroscopic enhancements were detected as function of gold conc...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Accademia Peloritana dei Pericolanti
2011-09-01
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| Series: | Atti della Accademia Peloritana dei Pericolanti : Classe di Scienze Fisiche, Matematiche e Naturali |
| Online Access: | http://dx.doi.org/10.1478/C1V89S1P064 |
| Summary: | The plasmon resonance of metallic Au/Ag alloys in the colloidal state was tuned from 400 nm to 500 nm using a laser irradiated technique, performed directly in the liquid state. Interesting optical nonlinearities, trapping effects and spectroscopic enhancements were detected as function of gold concentration in the nanoalloys. In particular a reduction of the limiting threshold was observed by increasing the gold amount. The SERS activity of the Au/Ag alloys was tested in liquid and in solid state in presence of linear carbon chains as probe molecules. The dependence of the increased Raman signals on the nanoparticle Au/Ag atomic ratio is presented and discussed. Finally preliminary studies and prospects for optical and Raman tweezers experiments are discussed. |
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| ISSN: | 0365-0359 1825-1242 |