Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing
Nickel silicides (NiSi) are renowned for their ability to withstand high temperatures and resist oxidation and corrosion in challenging environments. As a result, these alloys have garnered interest for potential applications in turbine blades and underwater settings. However, their high brittleness...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-09-01
|
Series: | Metals |
Subjects: | |
Online Access: | https://www.mdpi.com/2075-4701/13/9/1591 |
_version_ | 1797578793120956416 |
---|---|
author | Mohammad Ibrahim Qiang Du Even Wilberg Hovig Geir Grasmo Christopher Hulme Ragnhild E. Aune |
author_facet | Mohammad Ibrahim Qiang Du Even Wilberg Hovig Geir Grasmo Christopher Hulme Ragnhild E. Aune |
author_sort | Mohammad Ibrahim |
collection | DOAJ |
description | Nickel silicides (NiSi) are renowned for their ability to withstand high temperatures and resist oxidation and corrosion in challenging environments. As a result, these alloys have garnered interest for potential applications in turbine blades and underwater settings. However, their high brittleness is a constant obstacle that hinders their use in producing larger parts. A literature review has revealed that incorporating trace amounts of transition metals can enhance the ductility of silicides. Consequently, the present study aims to create NiSi-based powders with the addition of titanium (Ti), boron (B), cobalt (Co), molybdenum (Mo), and vanadium (V) for Additive Manufacturing (AM) through the process of gas atomization. The study comprehensively assesses the microstructure, phase composition, thermal properties, and surface morphology of the produced powder particles, specifically NiSi11.9Co3.4, NiSi10.15V4.85, NiSi11.2Mo1.8, and Ni-Si10.78Ti1.84B0.1. Commonly used analytical techniques (SEM, EDS, XRD, DSC, and laser diffraction) are used to identify the alloy configuration that offers optimal characteristics for AM applications. The results show spherical particles within the size range of 20–63 μm, and only isolated satellites were observed to exist in the produced powders, securing their smooth flow during AM processing. |
first_indexed | 2024-03-10T22:27:48Z |
format | Article |
id | doaj.art-3330ec6cbb33480989f82cddf05b3acd |
institution | Directory Open Access Journal |
issn | 2075-4701 |
language | English |
last_indexed | 2024-03-10T22:27:48Z |
publishDate | 2023-09-01 |
publisher | MDPI AG |
record_format | Article |
series | Metals |
spelling | doaj.art-3330ec6cbb33480989f82cddf05b3acd2023-11-19T11:57:05ZengMDPI AGMetals2075-47012023-09-01139159110.3390/met13091591Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive ManufacturingMohammad Ibrahim0Qiang Du1Even Wilberg Hovig2Geir Grasmo3Christopher Hulme4Ragnhild E. Aune5Department of Engineering Sciences, University of Agder (UiA), 4879 Grimstad, NorwaySINTEF Industry, Department of Metal Production and Processing, 0314 Oslo, NorwaySINTEF Industry, Department of Metal Production and Processing, 0314 Oslo, NorwayDepartment of Engineering Sciences, University of Agder (UiA), 4879 Grimstad, NorwayDepartment of Materials Science and Engineering, KTH Royal Institute of Technology, 114 28 Stockholm, SwedenDepartment of Engineering Sciences, University of Agder (UiA), 4879 Grimstad, NorwayNickel silicides (NiSi) are renowned for their ability to withstand high temperatures and resist oxidation and corrosion in challenging environments. As a result, these alloys have garnered interest for potential applications in turbine blades and underwater settings. However, their high brittleness is a constant obstacle that hinders their use in producing larger parts. A literature review has revealed that incorporating trace amounts of transition metals can enhance the ductility of silicides. Consequently, the present study aims to create NiSi-based powders with the addition of titanium (Ti), boron (B), cobalt (Co), molybdenum (Mo), and vanadium (V) for Additive Manufacturing (AM) through the process of gas atomization. The study comprehensively assesses the microstructure, phase composition, thermal properties, and surface morphology of the produced powder particles, specifically NiSi11.9Co3.4, NiSi10.15V4.85, NiSi11.2Mo1.8, and Ni-Si10.78Ti1.84B0.1. Commonly used analytical techniques (SEM, EDS, XRD, DSC, and laser diffraction) are used to identify the alloy configuration that offers optimal characteristics for AM applications. The results show spherical particles within the size range of 20–63 μm, and only isolated satellites were observed to exist in the produced powders, securing their smooth flow during AM processing.https://www.mdpi.com/2075-4701/13/9/1591additive manufacturing (AM)gas atomizationnickel silicide (NiSi)silicon (Si)nickel (Ni) |
spellingShingle | Mohammad Ibrahim Qiang Du Even Wilberg Hovig Geir Grasmo Christopher Hulme Ragnhild E. Aune Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing Metals additive manufacturing (AM) gas atomization nickel silicide (NiSi) silicon (Si) nickel (Ni) |
title | Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing |
title_full | Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing |
title_fullStr | Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing |
title_full_unstemmed | Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing |
title_short | Gas-Atomized Nickel Silicide Powders Alloyed with Molybdenum, Cobalt, Titanium, Boron, and Vanadium for Additive Manufacturing |
title_sort | gas atomized nickel silicide powders alloyed with molybdenum cobalt titanium boron and vanadium for additive manufacturing |
topic | additive manufacturing (AM) gas atomization nickel silicide (NiSi) silicon (Si) nickel (Ni) |
url | https://www.mdpi.com/2075-4701/13/9/1591 |
work_keys_str_mv | AT mohammadibrahim gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing AT qiangdu gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing AT evenwilberghovig gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing AT geirgrasmo gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing AT christopherhulme gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing AT ragnhildeaune gasatomizednickelsilicidepowdersalloyedwithmolybdenumcobalttitaniumboronandvanadiumforadditivemanufacturing |